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An efficient and low-cost photoanode for backside illuminated dye-sensitized solar cell using 3D porous alumina

Research Abstract

This paper presents a new strategy for developing back-side illuminated dye-sensitized solar cells (DSSCs) using nanoporous alumina substrate containing Cu impurities. The presence of a traces of Cu in the aluminum leads to the formation of 3D nanoporous anodic aluminum oxide (AAO) structure which consisted of an array of cylindrical pores interconnected by horizontal holes. Under different anodizing conditions, four different AAO substrates were fabricated and applied for developing DSSCs. The current-voltage characteristics of the DSSCs were measured and compared. Results obtained indicated that the performance (photocurrent density, open-circuit photovoltage and efficiency) of DSSCs based on 3D AAO was significantly enhanced compared to those of FTO/TiO2. The efficiencies of DSSCs based on alumina P90A, P90B and OX60 were improved by 172%, 51%, and 274%, respectively. The enhancement in photocurrent and efficiency is attributed to the reduction in the carrier recombination, uniform distribution of the dye molecules inside the vertical tubes, horizontal interconnections of pores as well as a reduction in pore size. This indicates that AAO based DSSCs can contribute significantly to energy harvesting from the sun.

Research Authors
Waleed A. El-Said, M. Abdel-Shakour, Alaa M. Abd-Elnaiem
Research Department
Research Journal
Materials Letters
Research Member
Research Pages
pp. 126–130
Research Publisher
Elsevier
Research Rank
1
Research Vol
Vol. 222
Research Website
https://www.sciencedirect.com/science/article/pii/S0167577X18305718
Research Year
2018

Design, synthesis, anticorrosion efficiency, and applications of novel Gemini surfactants for preparation of small-sized hollow spheres mesoporous silica Nanoparticles

Research Abstract

The unique properties of Gemini surfactants and their variety of applications encouraged many researchers
to synthesize more of these compounds. Herein, we constructed new cationic Gemini surfactants
by using aromatic spacers with different chain lengths. The critical micelle concentration value
for each surfactant was determined using the electrical conductivity measurements. The variety of aggregation
behaviors of Gemini surfactants was studied by using atomic force microscopy, which
encouraged us to use these surfactants in the preparation of mesoporous silica NPs. Our results indicated
that we have succeeded in finding a new soft-template for preparing uniform small size hollow spheres
mesoporous silica NPs of a diameter depending on the used surfactant. Moreover, we investigated the
effect of pH value on the morphology of the prepared silica, which indicated that using of acidic media
resulted in the formation of hollow micro-particles instead of hollow NPs. Furthermore, the anticorrosion
efficiency of these surfactants in comparing with cetyltrimethylammonium bromide (CTAB)
as a positive control was investigated by monitoring the corrosion rate of iron sheets in 0.5M of hydrochloric
acid based on weight loss method. Our results indicated that all the prepared Gemini surfactants
possessed higher anti-corrosion efficiency at very low concentrations than CTAB surfactant.

Research Authors
El-Said W.A., Moharram A.S., Hussein E.M., El-Khawaga A.M.
Research Department
Research Journal
Materials Chemistry and Physics
Research Pages
pp. 123-136
Research Publisher
NULL
Research Rank
1
Research Vol
Vol. 211
Research Website
NULL
Research Year
2018

Design, synthesis, anticorrosion efficiency, and applications of novel Gemini surfactants for preparation of small-sized hollow spheres mesoporous silica Nanoparticles

Research Abstract

The unique properties of Gemini surfactants and their variety of applications encouraged many researchers
to synthesize more of these compounds. Herein, we constructed new cationic Gemini surfactants
by using aromatic spacers with different chain lengths. The critical micelle concentration value
for each surfactant was determined using the electrical conductivity measurements. The variety of aggregation
behaviors of Gemini surfactants was studied by using atomic force microscopy, which
encouraged us to use these surfactants in the preparation of mesoporous silica NPs. Our results indicated
that we have succeeded in finding a new soft-template for preparing uniform small size hollow spheres
mesoporous silica NPs of a diameter depending on the used surfactant. Moreover, we investigated the
effect of pH value on the morphology of the prepared silica, which indicated that using of acidic media
resulted in the formation of hollow micro-particles instead of hollow NPs. Furthermore, the anticorrosion
efficiency of these surfactants in comparing with cetyltrimethylammonium bromide (CTAB)
as a positive control was investigated by monitoring the corrosion rate of iron sheets in 0.5M of hydrochloric
acid based on weight loss method. Our results indicated that all the prepared Gemini surfactants
possessed higher anti-corrosion efficiency at very low concentrations than CTAB surfactant.

Research Authors
El-Said W.A., Moharram A.S., Hussein E.M., El-Khawaga A.M.
Research Department
Research Journal
Materials Chemistry and Physics
Research Pages
pp. 123-136
Research Publisher
NULL
Research Rank
1
Research Vol
Vol. 211
Research Website
NULL
Research Year
2018

Design, synthesis, anticorrosion efficiency, and applications of novel Gemini surfactants for preparation of small-sized hollow spheres mesoporous silica Nanoparticles

Research Abstract

The unique properties of Gemini surfactants and their variety of applications encouraged many researchers
to synthesize more of these compounds. Herein, we constructed new cationic Gemini surfactants
by using aromatic spacers with different chain lengths. The critical micelle concentration value
for each surfactant was determined using the electrical conductivity measurements. The variety of aggregation
behaviors of Gemini surfactants was studied by using atomic force microscopy, which
encouraged us to use these surfactants in the preparation of mesoporous silica NPs. Our results indicated
that we have succeeded in finding a new soft-template for preparing uniform small size hollow spheres
mesoporous silica NPs of a diameter depending on the used surfactant. Moreover, we investigated the
effect of pH value on the morphology of the prepared silica, which indicated that using of acidic media
resulted in the formation of hollow micro-particles instead of hollow NPs. Furthermore, the anticorrosion
efficiency of these surfactants in comparing with cetyltrimethylammonium bromide (CTAB)
as a positive control was investigated by monitoring the corrosion rate of iron sheets in 0.5M of hydrochloric
acid based on weight loss method. Our results indicated that all the prepared Gemini surfactants
possessed higher anti-corrosion efficiency at very low concentrations than CTAB surfactant.

Research Authors
El-Said W.A., Moharram A.S., Hussein E.M., El-Khawaga A.M.
Research Department
Research Journal
Materials Chemistry and Physics
Research Member
Research Pages
pp. 123-136
Research Publisher
NULL
Research Rank
1
Research Vol
Vol. 211
Research Website
NULL
Research Year
2018

Thermal Annealing induced phase transition and UV Irradiation Induced brightening in CdS nanoparticles

Research Abstract

CdS nanoparticles were synthesized by co-precipitation method. Samples were annealed in air for 3hrs in the temperature range of 200-700°C to study the effect of annealing temperature (Ta) on structural, morphological and optical properties of CdS nanoparticles. Monodispersed CdS was UV irradiated to investigate photo-induced changes in the optical properties of the samples. Structural and optical properties were characterized using XRD, HRTEM, UV-vis absorption and FTIR spectroscopy. The increase in average crystallite size from 3 to 23 nm as a result of annealing has been estimated from XRD. Total phase transition at Ta = 300oC from as prepared Cubic to hexagonal CdS structure and to CdSO3 monoclinic structure at Ta = 700oC. Analysis of UV-vis absorption spectra, show remarkable decrease in optical band gap from 3.4 for as prepared to 2.5eV at 500oC with increasing Ta, as a result of enhancement in crystallinity and increase in particle size, which in turn leads to the reduction of quantum confinement effect. UV induced effect on CdS nanoparticles dispersed in double distilled water leads to an increase in the optical band gap (photo-brightening).

Research Authors
M. A. Osman
A. A. Othman
A. G. Abed-Elrahim
Research Department
Research Journal
Nanocon 2014 conference proceeding
Research Pages
NULL
Research Publisher
NULL
Research Rank
3
Research Vol
NULL
Research Website
http://www.nanocon.eu/files/proceedings/20/reports/3304.pdf
Research Year
2014

Lie algebra and Laguerre matrix polynomials of one variable

Research Abstract

The main object of this present paper is to introduce an extended family of Laguerre matrix polynomials and to derive a new class of certain summation formulas with the help of the Lie algebra method using techniques.

Research Authors
Ayman Shehata
Research Department
Research Journal
General Letters in Mathematics
Research Pages
1-5
Research Publisher
NULL
Research Rank
1
Research Vol
Vol. 4, No. 1
Research Website
http://www.refaad.com/Views/GLM/home.aspx
Research Year
2018

Inequalities for Tricomi functions

Research Abstract

In this study, we establish new two-sided inequalities for Tricomi functions. Some special and confluent cases of our main aim are established with the help of the inequalities for hypergeometric functions;_{0}F_{1}.

Research Authors
Ayman Shehata
Research Department
Research Journal
Malaya Journal of Matematik (MJM)
Research Pages
344 -348
Research Publisher
NULL
Research Rank
1
Research Vol
Vol. 6, No. 2
Research Website
www.malayajournal.org/selected_article.php?id=444
Research Year
2018

Extended Bessel matrix functions

Research Abstract

This work is devoted to the study of some new families of matrix functions which provide a further
extension of the extended Bessel matrix functions. In the sequel, some new and interesting properties of
these families of k-Bessel matrix functions have been investigated and the connections between k-Bessel
matrix functions and k-Laguerre matrix polynomials are indicated in the concluding section of the paper.

Research Authors
Ayman Shehata
Research Department
Research Journal
Mathematical Sciences and Applications E-Notes
Research Pages
1-11.
Research Publisher
NULL
Research Rank
1
Research Vol
Vol. 6, No. 1
Research Website
NULL
Research Year
2018

Certain generating relations of Konhauser matrix polynomials from the view point of Lie algebra method

Research Abstract

This paper is devoted to construct Lie operators associated with Konhauser matrix polynomials of the first kind using Lie group theory. Furthermore, certain generating matrix functions, integral representations, and matrix differential recurrence relations, new and known consequences for Konhauser matrix polynomials are derived and their applications are presented.

Research Authors
Ayman Shehata
Research Department
Research Journal
University Politechnica of Bucharest Scientific Bulletin- series A- Applied mathematics and physics
Research Pages
123-136
Research Publisher
NULL
Research Rank
1
Research Vol
Vol. 79, No. 4
Research Website
NULL
Research Year
2017

Some new results for Struve matrix functions

Research Abstract

This study deals with the convergence properties of Struve matrix functions within the complex analysis. Certain new classes of matrix differential recurrence relations, matrix differential equations, the various families of integral representations and integrals obtained here are believed to be new in the theory of Struve matrix functions, and the several properties of the modified Struve matrix functions are also included. Finally, we investigate the operational rules which yield a different view of the expansion formulae for Struve and modified Struve matrix functions.

Research Authors
Ayman Shehata
Research Department
Research Journal
Milan Journal of Mathematics
Research Pages
pp 81–96
Research Publisher
NULL
Research Rank
1
Research Vol
Vol.86, No.1
Research Website
NULL
Research Year
2018
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