Hierarchical porous zeolitic imidazolate frameworks (HZIFs) are promising materials for several applications, including adsorption, separation, and nanomedicine. Herein, the conversion of zinc hydroxide nitrate nanosheets into HZIF-8 nanocomposite with graphene oxide (GO) and magnetic nanoparticles (MNPs) is reported. The conversion takes place at room temperature in water. This approach has been successfully applied for the formation of leaf-like ZIF(ZIF-L), and their nanocomposites with nanoparticles, such as GO and MNPs. This method offers a simple approach for the synthesis of tunable pore structure using nanoparticles and fast room temperature conversion (30 min) without any visible residual impurities of zinc hydroxide nitrates. The applications of HZIF-8, ZIF-L, and their nanocomposites, for CO2 sorption, exhibit excellent adsorption properties. The synthesized composites exhibit enhanced CO2 adsorption capacity due to the synergistic effect between nanoparticles (GO, or MNPs), and ZIF-8. The materials have good potential for further applications.

The development of simple, low-cost, and specific detection method for mercury (Hg(II)) ions in aqueous media using matrix-assisted laser desorption ionization mass spectrometry (MALDI-MS) is a challenge due to matrix interferences and acidity that destroy weak interactions. Herein, a new binary matrix consists of mefenamic acid, and thymine (T) is applied for simple and specific detection of Hg(II) in aqueous solution and blood sample. Mass spectra show metal-to-ligand ratio of 1:2 (Hg(II):T) in which Hg(II) ions are bound to two T molecules and two water molecules, i.e., [Hg(T)2(H2O)2]. The method is simple and fast, and requires cheap reagents. In addition, the spectra show extremely specific signals for Hg(II) ions and insignificant signals in case of other competing metal ions. The concept of our protocol can be applied for other metals. The new matrix may be used for the analysis of small molecules with minimal interferences peaks.

This article deals with investigation of fine-scale precipitation in Al-Mg-Zn alloys with compositions of Al - 2 at% Mgx at% Zn, (x = 1.8, 2 and 4.2). The precipitates morphology was examined by scanning electron microscope (SEM) and correlated with the microhardness (HV) and differential scanning calorimetry (DSC) of the specimens. The precipitates are characterized as ’ (MgZn2) and  (MgZn2) phases of hexagonal structure of the same composition with a slight difference in lattice parameters. In addition, T-phase pf composition (Mg32 (Al, Zn)49) having a cubic crystal structure. Owing to the determined activation energies of the precipitates, the kinetics associated with their nucleation and growth can be characterized. The thermal energy acquired during aging leads to the agglomeration of precipitates to or larger particle sizes.

This article deals with investigation of fine-scale precipitation in Al-Mg-Zn alloys with compositions of Al - 2 at% Mgx at% Zn, (x = 1.8, 2 and 4.2). The precipitates morphology was examined by scanning electron microscope (SEM) and correlated with the microhardness (HV) and differential scanning calorimetry (DSC) of the specimens. The precipitates are characterized as ’ (MgZn2) and  (MgZn2) phases of hexagonal structure of the same composition with a slight difference in lattice parameters. In addition, T-phase pf composition (Mg32 (Al, Zn)49) having a cubic crystal structure. Owing to the determined activation energies of the precipitates, the kinetics associated with their nucleation and growth can be characterized. The thermal energy acquired during aging leads to the agglomeration of precipitates to or larger particle sizes.

This article deals with investigation of fine-scale precipitation in Al-Mg-Zn alloys with compositions of Al - 2 at% Mgx at% Zn, (x = 1.8, 2 and 4.2). The precipitates morphology was examined by scanning electron microscope (SEM) and correlated with the microhardness (HV) and differential scanning calorimetry (DSC) of the specimens. The precipitates are characterized as ’ (MgZn2) and  (MgZn2) phases of hexagonal structure of the same composition with a slight difference in lattice parameters. In addition, T-phase pf composition (Mg32 (Al, Zn)49) having a cubic crystal structure. Owing to the determined activation energies of the precipitates, the kinetics associated with their nucleation and growth can be characterized. The thermal energy acquired during aging leads to the agglomeration of precipitates to or larger particle sizes.

Network of new quaternary borate glasses Bi2O3–Y2O3–Al2O3–B2O3 was studied by FTIR and UV spectroscopies. According to the FTIR results, the addition of Y2O3 increases the amount of bridging oxygens and changes the coordination number of the glasses by creating [BO4] structural units. FTIR investigations explained the increase of the computed elastic moduli according to Makishima–Mackenzie model. The optical parameters such as the UV transmission, the polarizability, and the basicity are found to be sensitive to the concentration of Y2O3. The results of the elastic moduli and the optical parameters were interpreted in terms of the vibrations of structural groups and the strength of the bonds.

Network of new quaternary borate glasses Bi2O3–Y2O3–Al2O3–B2O3 was studied by FTIR and UV spectroscopies. According to the FTIR results, the addition of Y2O3 increases the amount of bridging oxygens and changes the coordination number of the glasses by creating [BO4] structural units. FTIR investigations explained the increase of the computed elastic moduli according to Makishima–Mackenzie model. The optical parameters such as the UV transmission, the polarizability, and the basicity are found to be sensitive to the concentration of Y2O3. The results of the elastic moduli and the optical parameters were interpreted in terms of the vibrations of structural groups and the strength of the bonds.

This study reports on the optical parameters of MoO3–V2O5–PbO films. The measured transmittance spectra in the spectral range 300–2500 nm was used for precise calculations of the complex index of refraction (real (n) and imaginary (k) parts) as well as the film thicknesses. With the addition of MoO3, a blue shift of the absorption edge was represented while the index of refraction (n) was decreased. The decrease of the index of refraction was discussed in terms of the dispersion model. A good correlation between the bulk modulus Kop, the optical band gap Eg and the index of refraction was observed. With the help of Kop, Eg and n values, the electronic polarizability has been calculated for the films under study. The results well discussed in terms of the density, electronegativity and polarizability changes due to the addition of MoO3 content.

In the present work, Al-Mg-Zn alloys with compositions of Al- 2 at.% Zn — x at.% Mg, (x=1.8, 2, 2.4, 3 and 4.2) have been investigated. The developed precipitates and their growth have been followed as a function of aging temperature. The precipitates morphology was examined by scanning electron microscope (SEM) and correlated with the microhardness (HV) and differential scanning calorimetry (DSC) of the specimens. The structure of the precipitates has been detected by X-ray diffraction (XRD). Mostly, the precipitates are characterized as T′, T, η′ and η phases. The XRD charts analysis show that T′(Mg32 (Al, Zn)49) and T (Mg32 (Al, Zn)49) are cubic whereas η′ (MgZn2) and η (MgZn2) are hexagonal.η′ andrη phases have had a hexagonal structure of the same composition with slight different lattice parameters .

In the present work, Al-Mg-Zn alloys with compositions of Al- 2 at.% Zn — x at.% Mg, (x=1.8, 2, 2.4, 3 and 4.2) have been investigated. The developed precipitates and their growth have been followed as a function of aging temperature. The precipitates morphology was examined by scanning electron microscope (SEM) and correlated with the microhardness (HV) and differential scanning calorimetry (DSC) of the specimens. The structure of the precipitates has been detected by X-ray diffraction (XRD). Mostly, the precipitates are characterized as T′, T, η′ and η phases. The XRD charts analysis show that T′(Mg32 (Al, Zn)49) and T (Mg32 (Al, Zn)49) are cubic whereas η′ (MgZn2) and η (MgZn2) are hexagonal.η′ andrη phases have had a hexagonal structure of the same composition with slight different lattice parameters .