Biobased adsorbents and membranes offer advantages related to resource efficiency, safety, and fast kinetics but have challenges related to their reusability and water flux. Nanocellulose/alginate composite hydrogel beads were successfully prepared with a diameter of about 3–4 mm and porosity as high as 99%. The beads were further modified with in situ TEMPO-mediated oxidation to functionalize the hydroxyl groups of cellulose and facilitate the removal of cationic pollutants from aqueous samples at low pressure, driven by electrostatic interactions. The increased number of carboxyl groups in the bead matrix improved the removal efficiency of the adsorbent without compromising the water throughput rate; being as high as 17000 L h⁻¹ m⁻² bar⁻¹. The absorptivity of the beads was evaluated with UV-vis for the removal of the dye Methylene Blue (91% removal) from spiked water and energy dispersive X-ray spectroscopy (EDS) and X-ray photoelectron spectroscopy (XPS) elemental analyses for the removal of Cd²⁺ from industrial mining effluents. The modified beads showed a 3-fold increase in ion adsorption and pose as excellent candidates for the manufacturing of three-dimensional (3-D) column filters for large-volume, high flux water treatment under atmospheric pressure.

A metal–organic framework (MOF) of cerium (Ce) ions and 4,4′,4′′-nitrilotribenzoic acid linker was synthesized via a hydrothermal method. Ce-MOF consists of a Lewis acid moiety, i.e. Ce³⁺ and triphenylamine cores. It showed Fenton-like properties with excellent catalytic oxidation activity for olefins, primary/secondary alcohols, and water pollutants e.g., organic dyes. It displayed high oxidation conversion of cinnamyl alcohol and styrene of 100% and 53%, respectively. It offered good selectivity towards styrene oxide and benzaldehyde (i.e. 75% and 100%, respectively). It was applied for the oxidative degradation of dyes e.g. rhodamine B (RhB), methyl blue (MeB), Congo red (CR), and direct blue (DB) using hydrogen peroxide (H₂O₂) as an oxidant. It exhibited high efficiency in the oxidative degradation of these water pollutants. The mechanistic study of oxidation involves the formation of radical hydroxyl (^•OH) species. This study revealed the possibility of enhancing the oxidative catalytic performance, including oxidative degradation of organic pollutants, by employing advanced oxidation processes (AOPs) using Ce-MOF. The catalyst is recyclable five times without significantly decreasing of the material’s catalytic performance.

The synthesis of magnetic nanoparticles enclosed in zeolitic imidazolate frameworks (MNPs@ZIF-8) was successful carried out at ambient temperature and atmospheric pressure. The synthesis procedure was selected because it is uncomplicated and does not call for the use of any sophisticated pieces of apparatus throughout its execution. The Fourier transform infrared (FT-IR), X-ray diffraction (XRD), and transmission electron microscopy (TEM) images were investigated to characterize the materials. The analysis of the data allowed MNPs@ZIF-8 to evolve into a highly crystalline phase with particles ranging in size from 50 to 100 nanometers. This was made feasible by the fact that the phase could be created. It was explored whether or not MNPs@ZIF-8 was effective as a nanocarrier for the delivery of natural medicines like crocin. It was demonstrated to be very biocompatible and had an IC₅₀ value of > 1000 μg/mL, which is the concentration at which half of the maximum inhibitory effect is produced. The IC₅₀ value for crocin-loaded MNPs-ZIF-8 was 419 ± 0 μg/mL, which was roughly half of the IC₅₀ value for pure crocin, which was 716 ± 160 μg/mL.

Metal-organic frameworks (MOFs) have advanced several applications, including energy, biomedical and environmental remediation. However, most of the reported MOF materials are in powder form limiting their applications. This study reported the processing of MOF via three-dimensional (3D) printing of cellulose-MOFs (denoted as CelloMOFs). The 3D printing procedure involved a one-pot method including three steps: gel formation, 3D printing, and in-situ growth of MOF crystals. This procedure offered 3D printing of CelloMOF via a binder-free method with high loading of 67.5 wt%. The 3D-printed porous structures were used as adsorbents for carbon dioxide (CO₂), dye, and heavy metal ions. They can be also used as catalysts for the degradation of water pollutants such as organic dyes. The materials can be separated easily without requiring extra procedures such as centrifugation or filtration. The materials offered complete (>99%) removal of organic dyes within 10 min with high selectivity toward anionic dyes e.g, methyl blue (MeB). The materials exhibited CO₂ and heavy metal ions adsorption capacities of 0.63 mmol/g (27.7 mg/g) and 8–328 mg/g, respectively, with good recyclability. Our methodology will open new venues for advanced 3D printing of CelloMOF and its applications for water treatment and air purification.

The development of porous organic polymers, specifically covalent organic frameworks (COFs), has facilitated the advancement of numerous applications. Nevertheless, the limited availability of COFs solely in powder form imposes constraints on their potential applications. Furthermore, it is worth noting that COFs tend to undergo aggregation, leading to a decrease in the number of active sites available within the material. This work presents a comprehensive methodology for the transformation of a COF into three-dimensional (3D) scaffolds using the technique of 3D printing. As part of the 3D printing process, a composite material called CelloCOF was created by combining cellulose nanofibrils (CNF), sodium alginate, and COF materials (i.e., COF-1 and COF-2). The intervention successfully mitigated the agglomeration of the COF nanoparticles, resulting in the creation of abundant active sites that can be effectively utilized for adsorption purposes. The method of 3D printing can be described as a simple and basic procedure that can be adapted to accommodate hierarchical porous materials with distinct micro- and macropore regimes. This technology demonstrates versatility in its use across a range of COF materials. The adsorption capacities of 3D CelloCOF materials were evaluated for three different adsorbates: carbon dioxide (CO₂), heavy metal ions, and perfluorooctanesulfonic acid (PFOS). The results showed that the materials exhibited adsorption capabilities of 19.9, 7.4–34, and 118.5–410.8 mg/g for CO₂, PFOS, and heavy metals, respectively. The adsorption properties of the material were found to be outstanding, exhibiting a high degree of recyclability and exceptional selectivity. Based on our research findings, it is conceivable that the utilization of custom-designed composites based on COFs could present new opportunities in the realm of water and air purification.

Metal–organic frameworks (MOFs) improved several trends and are promising for industrial applications. However, current synthesis processes offer powder form, rendering their applications difficult. A simple solvothermal method offered an in situ growth of copper-based MOFs, for example, CuBDC (BDC: benzene-1,4-dicarboxylic acid) into a cotton textile; the material was denoted as CuBDC@Textile. CuBDCTextile was used as a solid sensor and adsorbent for volatile organic compounds (VOCs). It exhibited good vapochromic properties that enabled a colorimetric detection of pyridine (Py) via naked eyes with high selectivity and good sensitivity. Adsorption of pyridine via pervaporation using CuBDC@Textile was recorded. CuBDCTextile is a flexible textile with a high adsorption capacity (137.9 mg g⁻¹) toward pyridine. It offered dual functional: sensor probe and adsorbent. The synthesis of CuBDC@Textile and their excellent performance as a sensor and adsorbent are promising for further investigation of the “MOFs on textile materials” topic.

Background

Mesocoeliidae is a common parasite of the small intestine of amphibians and reptiles. From Egypt, only Mesocoelium monas (Rudolphi C., Berolini 811 (1819)) (Freitas JF, Revista Brasiliera de Biologia 18:171-174, (1958)) was reported and described by (Saad AI et. al., J Egypt Ger Soc Zool 33: 219-234, (2000)) from the small intestine of the Egyptian toads Bufo regularis from Aswan Governorate, Upper Egypt, and the molecular characterization of the same parasite was reported by (Mansour MFA et. al., Egypt. J. Biol. (Zool.),10:(1)1-8, (2014)) without any morphological description from the same final host. The present study aimed to detect the prevalence and the characteristic morphological features of mesocoeliid parasites of the Egyptian toads Bufo regularis.

Methods

Toads were collected from Assiut and Giza Governorates during the autumn of 2018. They were dissected and examined by a dissecting microscope for intestinal parasites. The collected trematodes were fixed, stained, dehydrated, cleared, and mounted. Photomicrographs were taken and parasite measurements were determined. Some of the identified worms were prepared for scanning electron microscope for studying their ultrastructure.

Results

Mesocoelium sociale was detected from the small intestine of 14 out of 51 toads Bufo regularis (27.5%) with worm burden (10–30 worms per host). Detailed morphometric characteristic features of the parasite were described by a light microscope. Scanning electron microscopy showed many fine ultrastructure details in the present study and confirmed the light microscopic description.

Conclusion

Mesocoelium sociale (Luhe M, Centralblatt für Bakteriologie Parasitenkunde und Infektionsk-rankheiten, 30, 166-177, (1901)) (Odhner T., Res. Swedish Zool Exped Egypt iv, (23a), 1–166, (1910)) is recorded for the first time from Egypt as a trematode parasite of the Egyptian toads’ Bufo regularis and described by a light microscope. In addition, it is described for the first time worldwide by scanning electron microscopy.

Linguatula serrata is a neglected parasitic zoonosis with less research recorded throughout the globe on the physiological and immunological alteration of dogs infested by these zoonotic parasites. This study aimed to evaluate the effects of L. serrata infestation on the dogs after experimental infestation with the nymphs by determining oxidative stress levels and immunological genes of cellular immunity. Larvae of L. serrata were collected from the infested goat mesenteric lymph nodes by cutting it, and the nymphs were liberated; these nymphs were mixed with saline at 37–40 °C for experimental infestation of dogs and observed infestation to puppies using viable nymphal stages (movable, not traumatized or dead). Blood and sera samples were sampled from the dog after 6 months of infestation. The nasal mucosa and its mucus were collected from the infested dogs as well as negative controls for evaluation of …

The chicken business faces substantial economic losses due to the risk of parasitic coinfection. Because the current study aimed to investigate enteric parasitic coinfections problems among the suspected examined chicken farms, samples were collected during the field investigation from suspected freshly dead birds, clinically diseased, apparently healthy, and litter samples for further laboratory parasitological, histopathological, and immunological examinations. Variable mortalities with various clinical indicators, such as ruffled feathers, weight loss, diarrhea of various colors, and a decline in egg production, occurred on the farms under investigation. In addition, the treatment protocols of each of the farms that were evaluated were documented and the m-RNA levels of some cytokines and apoptotic genes among the infected poultry have been assessed. The prevalence rate of parasitic coinfection in the current …