Synthesis, Structural Studies and Antimicrobial Activities of Manganese, Nickel and Copper Complexes of Two New Tridentate 2-Formylpyridine Thiosemicarbazone Ligands
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It is commonly accepted that the horizontal-to-vertical spectral ratio (HVSR) technique enables the detection of the
fundamental resonance frequency (fHVSR) of a given site. The
utility of this fHVSR is analyzed using the nonlinear regression
relationships between fHVSR and bedrock depth (h). The derived
relationships are mostly site-specific, so that the present paper
consists of two main parts. The first is a literature review for the
available empirical relationships between fHVSR and h. The aim of
this part is to highlight the practical limitations of these established
relationships and to make fair comparisons. The second is to
generate new relationships, taking advantage of the very wide
range of available lithological, geophysical, and geotechnical
borehole drilling data of the 697 KiK-NET seismic stations in
Japan. For this purpose, HVSR are calculated using 10,000 weak
earthquakes or linear events recorded at KiK-NET stations to
determine the fHVSR and correlate it with the corresponding h. The
overlying layers/bedrock interface falling within sedimentary,
igneous, or metamorphic layers significantly affect the derived
frequency–depth relationships. In addition, these relationships are
strongly reproduced by the Vp=Vs ratio of the bedrock in the range
of 1.6–2.2. Interestingly, it is found that fHVSR less than 1 Hz
corresponding to h more than 100 m leads the trend of the overall frequency–depth relationship.
A copper sulfide precursor of the general formula Cu(C13H9O2NCl)2(H2O)2 {C13H9O2NCl = 2-(2-chlorophenylamino)benzoate} was synthesized and routinely characterized regarding its CHN content, solution molar conductivity, powder X-ray diffraction (PXRD) pattern, magnetic moment and IR spectroscopic data. Copper sulfide Cu1.90S nanoparticles (CSNPs) were hydrothermally grown from this precursor and thiourea. The NPs were characterized by means of elemental analyses, PXRD and transmission electron microscopy (TEM). Brunauer–Emmett–Teller (BET) surface area measurements assigned mesoporous structure and an average pore diameter of 14.342 nm for the as-prepared NPs. The microbial resistance against common antimicrobial agents and the development of new microbial strains are urging factors for finding alternate potent antimicrobial agents. The as-prepared CSNPs may conquer plant diseases, as they exhibited antifungal efficiency against eleven phytopathogenic fungal isolates with Fusarium oxysporum growth reduction reaching 52.63%. Additionally, these NPs strongly inhibited the cellulase enzyme activity produced by Fusarium camptoceras by 51.54% at 30 °C and also inhibited the enzyme activity produced by Trichoderma harzianum by 55.4% at 40 °C leading to promising usefulness of the as prepared CSNPs in improving the quality and quantity of agricultural crops and protecting them from several plant diseases.
A copper sulfide precursor of the general formula Cu(C13H9O2NCl)2(H2O)2 {C13H9O2NCl = 2-(2-chlorophenylamino)benzoate} was synthesized and routinely characterized regarding its CHN content, solution molar conductivity, powder X-ray diffraction (PXRD) pattern, magnetic moment and IR spectroscopic data. Copper sulfide Cu1.90S nanoparticles (CSNPs) were hydrothermally grown from this precursor and thiourea. The NPs were characterized by means of elemental analyses, PXRD and transmission electron microscopy (TEM). Brunauer–Emmett–Teller (BET) surface area measurements assigned mesoporous structure and an average pore diameter of 14.342 nm for the as-prepared NPs. The microbial resistance against common antimicrobial agents and the development of new microbial strains are urging factors for finding alternate potent antimicrobial agents. The as-prepared CSNPs may conquer plant diseases, as they exhibited antifungal efficiency against eleven phytopathogenic fungal isolates with Fusarium oxysporum growth reduction reaching 52.63%. Additionally, these NPs strongly inhibited the cellulase enzyme activity produced by Fusarium camptoceras by 51.54% at 30 °C and also inhibited the enzyme activity produced by Trichoderma harzianum by 55.4% at 40 °C leading to promising usefulness of the as prepared CSNPs in improving the quality and quantity of agricultural crops and protecting them from several plant diseases.
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