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A Hollow Microtubular Triazine‐ and Benzobisoxazole‐Based Covalent Organic Framework Presenting Sponge‐Like Shells That Functions as a High‐Performance Supercapacitor

Research Abstract

In this paper we report the construction of a hollow microtubular triazine‐ and benzobisoxazole‐based covalent organic framework (COF) presenting a sponge‐like shell through a template‐free [3+2] condensation of the planar molecules 2,4,6‐tris(4‐formylphenyl)triazine (TPT‐3CHO) and 2,5‐diaminohydroquinone dihydrochloride (DAHQ‐2HCl). The synthesized COF exhibited extremely high crystallinity, a high surface area (ca. 1855 m2 g−1), and ultrahigh thermal stability. Interestingly, a time‐dependent study of the formation of the hollow microtubular COF having a sponge‐like shell revealed a transformation from initial ribbon‐like crystallites into a hollow tubular structure, and confirmed that the hollow nature of the synthesized COF was controlled by inside‐out Ostwald ripening, while the non‐interaction of the crystallites on the outer surface was responsible for the sponge‐like surface of the tubules. This COF exhibited significant supercapacitor performance: a high specific capacitance of 256 F g−1 at a current density of 0.5 A g−1, excellent cycling stability (98.8 % capacitance retention over 1850 cycles), and a high energy density of 43 Wh kg−1. Such hollow structural COFs with sponge‐like shells appear to have great potential for use as high‐performance supercapacitors in energy storage applications.

Research Authors
Ahmed F. M. El‐Mahdy, Ying‐Hui Hung, Tharwat Hassan Mansoure, Hsiao‐Hua Yu, Tao Chen, Shiao‐Wei Kuo
Research Department
Research Journal
Chemistry—An Asian Journal
Research Pages
1429- 1435
Research Publisher
wiley online library
Research Rank
1
Research Vol
14
Research Website
https://onlinelibrary.wiley.com/journal/1861471x
Research Year
2019

Ultrastable tetraphenyl-p-phenylenediaminebased covalent organic frameworks as platforms for high-performance electrochemical supercapacitors

Research Abstract

In this study we synthesized two tetraphenyl-p-phenylenediaminebased covalent organic frameworks (TPPDA-TPPyr and TPPDATPTPE COFs) for potential use in high-performance electrochemical supercapacitors. This excellent performance arose from their structures containing redox-active triphenylamine derivatives and their high surface areas.

Research Authors
Ahmed F. M. EL-Mahdy, Mohamed Gamal Mohamed, Tharwat Hassan Mansoure, Hsiao-Hua Yu, Tao Chen, Shiao-Wei Kuo
Research Date
Research Department
Research Journal
Chemical Communications
Research Pages
14890- 14893
Research Publisher
Royal Society of Chemisttry
Research Vol
55
Research Website
https://onlinelibrary.wiley.com/journal/1861471x
Research Year
2019

Ultrastable tetraphenyl-p-phenylenediamine-based covalent organic frameworks as platforms for high-performance electrochemical supercapacitors

Research Abstract

In this study we synthesized two tetraphenyl-p-phenylenediaminebased covalent organic frameworks (TPPDA-TPPyr and TPPDATPTPE COFs) for potential use in high-performance electrochemical supercapacitors. This excellent performance arose from their structures containing redox-active triphenylamine derivatives and their high surface areas.

Research Authors
Ahmed F. M. EL-Mahdy, Mohamed Gamal Mohamed, Tharwat Hassan Mansoure, Hsiao-Hua Yu, Tao Chen, and Shiao-Wei Kuo
Research Journal
Chemical Communications
Research Pages
14890-14893
Research Publisher
Royal Society of Chemistry
Research Rank
1
Research Vol
55
Research Website
https://pubs.rsc.org/en/journals/journalissues/cc?&_ga=2.172949411.1056702192.1597429047-1016307548.1550135456#!recentarticles&adv
Research Year
2019

Trichosporon jirovecii infection of red swamp crayfish (Procambarus clarkii)

Research Abstract

One hundred and twenty‐nine isolates of Trichosporon jirovecii were isolated from the melanized exoskeleton as well as eyestalks, gills, muscle and haemolymph of red swamp crayfish (Procambarus clarkii) collected from the River Nile, during summer 2015. Isolates were similar morphologically, biochemically and genetically. Also, random amplified polymorphic DNA (RAPD) analysis exhibited no polymorphism among the tested isolates. Virulence factors such as chitinase, protease, lipase activities and biofilm formation were examined. Challenge test, using a representative isolate (Tj_ASU8), proved its pathogenicity against crayfish. Magnesium oxide nanoparticles had a good antifungal activity with a minimum fungicidal concentration of 8 mg/ml. To the best of our knowledge, this is the first report for isolation of T. jirovecii from red swamp crayfish, showing melanization, from the River Nile. We assume that infected crayfish may act as a vector for this fungus and can disseminate infection to all susceptible hosts in the vicinity.

Research Authors
Ebtsam Sayed Hassan Abdallah, Mahmoud Mostafa Mahmoud,Ismail Ramadan Abdel-rahim
Research Journal
Journal of Fish Diseases
Research Pages
NULL
Research Publisher
Wiley
Research Rank
1
Research Vol
NULL
Research Website
https://onlinelibrary.wiley.com/doi/epdf/10.1111/jfd.12879
Research Year
2018

Trichosporon jirovecii infection of red swamp crayfish (Procambarus clarkii)

Research Abstract

One hundred and twenty‐nine isolates of Trichosporon jirovecii were isolated from the melanized exoskeleton as well as eyestalks, gills, muscle and haemolymph of red swamp crayfish (Procambarus clarkii) collected from the River Nile, during summer 2015. Isolates were similar morphologically, biochemically and genetically. Also, random amplified polymorphic DNA (RAPD) analysis exhibited no polymorphism among the tested isolates. Virulence factors such as chitinase, protease, lipase activities and biofilm formation were examined. Challenge test, using a representative isolate (Tj_ASU8), proved its pathogenicity against crayfish. Magnesium oxide nanoparticles had a good antifungal activity with a minimum fungicidal concentration of 8 mg/ml. To the best of our knowledge, this is the first report for isolation of T. jirovecii from red swamp crayfish, showing melanization, from the River Nile. We assume that infected crayfish may act as a vector for this fungus and can disseminate infection to all susceptible hosts in the vicinity.

Research Authors
Ebtsam Sayed Hassan Abdallah, Mahmoud Mostafa Mahmoud,Ismail Ramadan Abdel-rahim
Research Journal
Journal of Fish Diseases
Research Pages
NULL
Research Publisher
Wiley
Research Rank
1
Research Vol
NULL
Research Website
https://onlinelibrary.wiley.com/doi/epdf/10.1111/jfd.12879
Research Year
2018

Trichosporon jirovecii infection of red swamp crayfish (Procambarus clarkii)

Research Abstract

One hundred and twenty‐nine isolates of Trichosporon jirovecii were isolated from the melanized exoskeleton as well as eyestalks, gills, muscle and haemolymph of red swamp crayfish (Procambarus clarkii) collected from the River Nile, during summer 2015. Isolates were similar morphologically, biochemically and genetically. Also, random amplified polymorphic DNA (RAPD) analysis exhibited no polymorphism among the tested isolates. Virulence factors such as chitinase, protease, lipase activities and biofilm formation were examined. Challenge test, using a representative isolate (Tj_ASU8), proved its pathogenicity against crayfish. Magnesium oxide nanoparticles had a good antifungal activity with a minimum fungicidal concentration of 8 mg/ml. To the best of our knowledge, this is the first report for isolation of T. jirovecii from red swamp crayfish, showing melanization, from the River Nile. We assume that infected crayfish may act as a vector for this fungus and can disseminate infection to all susceptible hosts in the vicinity.

Research Authors
Ebtsam Sayed Hassan Abdallah, Mahmoud Mostafa Mahmoud,Ismail Ramadan Abdel-rahim
Research Journal
Journal of Fish Diseases
Research Member
Research Pages
NULL
Research Publisher
Wiley
Research Rank
1
Research Vol
NULL
Research Website
https://onlinelibrary.wiley.com/doi/epdf/10.1111/jfd.12879
Research Year
2018

Pathogenicity of three entomopathogenic
fungi against the Mediterranean fruit fly,
Ceratitis capitata (Wiedemann)
(Diptera: Tephritidae)

Research Abstract

The use of pesticides against the Mediterranean fruit fly, Ceratitis capitata (Wiedemann) (Diptera: Tephritidae) as a
tool to control the pest has become an obstacle to the fresh agricultural products export to many countries that
restrict pesticides residues. The effectiveness of three local strains of entomopathogenic fungi: Metarhizium
anisopliae, Beauveria bassiana, and Paecilomyces lilacinus against the adult and immature stages of C. capitata was
evaluated under laboratory conditions. Obtained results showed that M. anisopliae and B. bassiana were superior in
its pathogenicity and potential to kill the pest than P. lilacinus. These results may be important to be used for the
control of the pest in IPM program.

Research Authors
N. A. Soliman, Sherihan M. Al-amin, Amira E. Mesbah, Ahmed M. A. Ibrahim and Ali M.A. Mahmoud
Research Department
Research Journal
Egyptian Journal of
Biological Pest Control
Research Member
Research Pages
Article number 49
Research Publisher
Springer
Research Rank
1
Research Vol
30
Research Website
https://link.springer.com/content/pdf/10.1186/s41938-020-00235-y.pdf
Research Year
2020

Pathogenicity of three entomopathogenic
fungi against the Mediterranean fruit fly,
Ceratitis capitata (Wiedemann)
(Diptera: Tephritidae)

Research Abstract

The use of pesticides against the Mediterranean fruit fly, Ceratitis capitata (Wiedemann) (Diptera: Tephritidae) as a
tool to control the pest has become an obstacle to the fresh agricultural products export to many countries that
restrict pesticides residues. The effectiveness of three local strains of entomopathogenic fungi: Metarhizium
anisopliae, Beauveria bassiana, and Paecilomyces lilacinus against the adult and immature stages of C. capitata was
evaluated under laboratory conditions. Obtained results showed that M. anisopliae and B. bassiana were superior in
its pathogenicity and potential to kill the pest than P. lilacinus. These results may be important to be used for the
control of the pest in IPM program.

Research Authors
N. A. Soliman, Sherihan M. Al-amin, Amira E. Mesbah, Ahmed M. A. Ibrahim and Ali M.A. Mahmoud
Research Department
Research Journal
Egyptian Journal of
Biological Pest Control
Research Pages
Article number 49
Research Publisher
Springer
Research Rank
1
Research Vol
30
Research Website
https://link.springer.com/content/pdf/10.1186/s41938-020-00235-y.pdf
Research Year
2020

Synthesis of CZTS without sulfurization process and its performance evaluation on n-Si substrate as ITO-free photovoltaic cell

Research Abstract

Kesterite Cu2ZnSnS4 (CZTS) nanostructure is synthesized without the sulfurization process using a solvothermal technique. The induced effects in the optical properties of the fabricated film of this nanostructure are studied. As XRD analysis revealed the as-prepared film is polycrystalline in nature which indexed in the tetragonal Kesterite structure of the CZTS phase. Optical properties related to solar cell parameters, such as absorption coefficient, penetration depth, Urbach energy, and energy band gap are studied. The absorption coefficient of 1.5 � 105 cm

Research Authors
N.M. Shaalan, A. Z. Mahmoud, D. Hamad
Research Department
Research Journal
Materials Science in Semiconductor Processing
Research Pages
pp 105318
Research Publisher
NULL
Research Rank
1
Research Vol
Volume 120
Research Website
NULL
Research Year
2020

Synthesis of CZTS without sulfurization process and its performance evaluation on n-Si substrate as ITO-free photovoltaic cell

Research Abstract

Kesterite Cu2ZnSnS4 (CZTS) nanostructure is synthesized without the sulfurization process using a solvothermal technique. The induced effects in the optical properties of the fabricated film of this nanostructure are studied. As XRD analysis revealed the as-prepared film is polycrystalline in nature which indexed in the tetragonal Kesterite structure of the CZTS phase. Optical properties related to solar cell parameters, such as absorption coefficient, penetration depth, Urbach energy, and energy band gap are studied. The absorption coefficient of 1.5 � 105 cm

Research Authors
N.M. Shaalan, A. Z. Mahmoud, D. Hamad
Research Department
Research Journal
Materials Science in Semiconductor Processing
Research Member
Research Pages
pp 105318
Research Publisher
NULL
Research Rank
1
Research Vol
Volume 120
Research Website
NULL
Research Year
2020
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