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The Catalytic Performance of Ultrasonically Prepared AlPO4 Nanocatalysts for the Selective Production of Dimethyl Ether from Methanol

Research Abstract

Conversion of methanol to dimethyl ether (MTD) has known to be one of the main routes for the production of a clean bio-fuel, i.e., dimethyl ether (DME). However, efficient, selective, and stable catalyst is highly required for production of DME especially at relatively low temperature. Herein, aluminum phosphate nanocatalysts were fabricated by a co-precipitation method in the presence of triethylamine (TEA) as a surfactant. Thermal, structural, spectroscopic, morphological and texture properties of the catalysts were characterized by thermal analyses (TG–DTA), X-Ray diffraction (XRD), Fourier transform infrared (FTIR), high resolution transmission electron microscopy (HR-TEM) and N2-sorption analyses. In addition, the acidity of these catalysts was evaluated by isopropyl alcohol dehydration and chemisorption of basic probes. Results of acidity and pyridine-TPD indicated that these catalysts possessed Brϕnsted acidic sites of weak and intermediate strengths. The results of catalytic activity demonstrated that aluminum phosphate nanocatalyst (AP1T1) calcined at 400 °C exhibited the best catalytic performance for methanol dehydration into DME with a conversion of 100% and a 100% selectivity at 250 °C. In addition, this catalyst (AP1T1) exhibits a unique behavior where its catalytic performance only decreases by 10% upon increasing the % of methanol in the reacting feed to 35%. Moreover, it possessed excellent long-term stability with almost the same efficiency after a period of 120 h. The observable catalytic activity of these catalysts was well linked to the catalyst acidity and the activation energy.

Research Authors
Abd El-Aziz Ahmed Said, Mohamed Nady Goda, Aya Ali Shaban
Research Date
Research Department
Research Journal
Catalysis Letters
Research Publisher
Springer Nature
Research Rank
Q3
Research Website
https://link.springer.com/article/10.1007/s10562-021-03664-y
Research Year
2021

Superior Competitive Adsorption Capacity of Natural Bentonite in the Efficient Removal of Basic Dyes from Aqueous Solutions

Research Abstract

In this study, natural bentonite has been used as a highly efficient, and low-cost sorbent for the adsorptive removal of methylene blue (MB), crystal violet (CV), and fuchsine basic (FB) dyes from aqueous solutions. X-ray fluorescence (XRF), Thermogravimetry and differential thermal analyses (TG-DTA), X-ray diffraction (XRD), Scanning electron microscopy (SEM), and Fourier transform infrared (FTIR) analyses for bentonite clay were performed. Results revealed that bentonite is an excellent sorbent for the elimination of these dyes with maximum adsorption capacities of 598.8, 929.7 and 875.2 mg g−1 for MB, CV, and FB, respectively. In addition, thermodynamic results reflected that the adsorption process is a spontaneous, endothermic, and of chemisorption nature. While kinetic studies specified that the adsorption of these dyes is ruled by the film diffusion and pore diffusion mechanism. Moreover, simultaneous removal of these dyes from their binary and ternary mixtures was also examined. A Regeneration study demonstrated that, bentonite can be recycled several times with almost the same efficiency.

Research Authors
Abd El-Aziz Ahmed Said and Mohamed Nady Goda
Research Date
Research Department
Research Journal
ChemistrySelect
Research Pages
2790-2803
Research Publisher
https://chemistry-europe.onlinelibrary.wiley.com/doi/full/10.1002/slct.202100575
Research Rank
Q3
Research Vol
6
Research Website
https://chemistry-europe.onlinelibrary.wiley.com/doi/full/10.1002/slct.202100575
Research Year
2021

L-fuzzifying soft preproximities

Research Abstract

The subject of the paper is the description of the category as objects L-fuzzifying soft preproximity spaces with structure preserving morphisms. We investigate the functorial relations between L-fuzzifying soft preproximity spaces and L-fuzzifying soft topological spaces. @ 2018 Academic Publications, Ltd.

Research Authors
O. R. Sayed, M. Azab Abd-Allah and Y. C. Kim
Research Department
Research File
Research Journal
International Journal of Pure and Applied Mathematics
Research Member
Research Pages
477-490
Research Vol
118 (2)
Research Website
http://www.ijpam.eu
Research Year
2018

(L, M)- fuzzy soft quasi-coincident neighborhood spaces

Research Abstract

In this paper, we introduce the concepts of (L;M)-fuzzy soft quasi-coincident neighborhood spaces and study their properties, where L be a completely distributive lattice with 0 and 1 elements and M be a strictly two-sided, commutative quantile lattice. Also, the relationships between these concepts were investigated. Furthermore, a characterization of LFS-continuous and LSN-mappings were given. @2017 Sayed, Elsanousy, Raghp and Kim.

Research Authors
O. R. Sayed, E. El-Sanousy, Y. H. Raghp and Yong Chan Kim
Research Department
Research Journal
Journal of Mathematical and computational Science
Research Member
Research Pages
321-334
Research Vol
7 (2)
Research Website
http://scik.org
Research Year
2017

A decomposition of soft continuity in soft topological spaces

Research Abstract

Introducing the notions of soft t-sets, soft t*-sets, soft B-sets, soft α*-sets and
soft C-sets in the setting of soft topological spaces, we study some of its properties and investigate the relationships between them besides considering some variants of continuous maps on soft topological spaces.

©2017 African Mathematical Union and Springer-Verlag Berlin Heidelberg
 

Research Authors
O. R. Sayed, N. Hassan and A. M. Khalil
Research Department
Research Journal
Afrika Matematika
Research Member
Research Pages
887–898
Research Vol
28
Research Website
DOI 10.1007/s13370-017-0494-8
Research Year
2017

On (L, M)- fuzzy soft topological spaces

Research Abstract

In this paper, the concepts of (L;M)-fuzzy soft topological spaces, (L;M)-fuzzy soft base and (L; M)-fuzzy soft filter spaces were introduced and their properties were studied, where L be a completely distributive lattice with 0 and 1 elements and M be a strictly two-sided, commutative quantile lattice. Also, the relationships between these concepts were investigated.

@2017 Sayed, Elsanousy, Raghp and Kim.

Research Authors
O. R. Sayed, E. El-Sanousy, Y. H. Raghp and Yong Chan Kim
Research Department
Research Journal
Journal of Mathematical and computational Science
Research Member
Research Pages
280-291
Research Vol
7 (2)
Research Website
http://scik.org
Research Year
2017

Fuzzy soft expert system in prediction of coronary artery disease

Research Abstract

Coronary artery disease affects millions of people all over the world including a major portion in Egypt every year. Although much progress has been done in
medical science, early detection of this disease is still a challenge for prevention. In this paper we, will extend the concept of fuzzy soft set theory so as to develop a
knowledge-based system in medicine and devise a prediction system named fuzzy soft expert system consisting of four main components. These are a fuzzification which translates inputs into fuzzy values, fuzzification of data sets to obtain fuzzy soft sets, a new fuzzy soft set by normal parameter reduction of fuzzy soft set and an algorithm to produce the resultant output. The fuzzy soft expert system developed is then used to predict for coronary artery disease using systolic blood pressure, low-density lipoprotein cholesterol, maximum heart rate, blood sugar, old peak and age of patients. A preliminary study is conducted on nine male patients undergoing treatment in the Cardiac Unit of the Faculty of Medicine, Assiut University, Egypt. It is found that the fuzzy soft expert system developed is able is to help the expert doctor to decide whether a patient needs to be given drug therapy or intervention.

@2016 Taiwan Fuzzy Systems Association and Springer-Verlag Berlin Heidelberg.
 

Research Authors
N. Hassan, O. R. Sayed, A. M. Khalil and M. Abdel Ghany
Research Department
Research Journal
International Journal of Fuzzy Systems
Research Member
Research Pages
1546–1559
Research Vol
19 (5)
Research Website
DOI 10.1007/s40815-016-0255-0
Research Year
2017

Local β compact spaces as fuzzy predicates defined in Łukasiewicz logic

Research Abstract

In this paper, some characterizations of fuzzifying β -compactness are given, including characterizations in terms of nets and β -subbases. Several characterizations of locally β -compactness in the framework of fuzzifying topology are introduced and the mapping theorems are obtained.

@ 2015 – IOS Press and the authors.
 

Research Authors
O. R. Sayed and Y. C. Kim
Research Department
Research Journal
Journal of Intelligent & Fuzzy Systems
Research Member
Research Pages
165-176
Research Vol
32 (1)
Research Website
DOI: 10.3233/JIFS-151335.
Research Year
2017

Soft topology and soft proximity as fuzzy predicates by formulae of Łukasiewicz logic

Research Abstract

In this paper, based in the Lukasiewicz logic, the definition of fuzzifying soft neighborhood structure and fuzzifying soft continuity are introduced. Also, the fuzzifying soft proximity spaces which are a generalization of the classical soft proximity spaces are given. Several theorems on classical soft proximities are special cases of the theorems we prove in this paper.

@University of Sistan and Baluchestan, Iran.

Research Authors
O. R. Sayed and R. A. Borzooei
Research Department
Research Journal
Iranian Journal of Fuzzy Systems
Research Member
Research Pages
153-168
Research Vol
13 (7)
Research Year
2016

An extensive study of supra generalized pre- regular closed sets

Research Abstract

The purpose of this paper is to study the concept of gpr μ  - closure and gpr μ -interior. Also, some more results of gpr μ - continuous functions are investigated. @2016 Academic Publications, Ltd.

doi: 10.12732/ijpam.v106i6.7

Research Authors
O. R. Sayed, G. Hango and V. Menon
Research Department
Research Journal
International Journal of Pure and Applied Mathematics
Research Member
Research Pages
37-57
Research Vol
106 (6)
Research Website
http://www.ijpam.eu
Research Year
2016
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