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Isolation and crystal structure of the first Pr(IV) coordination polymer and the complex anti-proliferative activity evaluation against seven cancer cell lines

Research Authors
Aref A.M. Aly, Ahmed B.M. Ibrahim, Amna S.A. Zidan, Hanan K. Mosbah, Sara A. Atta, Isabel Schicht, Alexander Villinger
Research Date
Research Department
Research Pages
132508
Research Publisher
Journal of Molecular Structure
Research Vol
1256
Research Website
https://www.sciencedirect.com/science/article/abs/pii/S0022286022001818
Research Year
2022

Trivalent cobalt complexes with NNS tridentate thiosemicarbazones: preparation, structural Study and investigation of antibacterial activity and cytotoxicity against human breast cancer cells

Research Authors
Amany Fathy, Ahmed B.M. Ibrahim, S. Abd Elkhalik, Alexander Villinger, S.M. Abbas
Research Date
Research Department
Research Journal
Inorganics
Research Pages
145
Research Vol
10
Research Website
https://www.mdpi.com/2304-6740/10/9/145
Research Year
2022

Thiosemicarbazones and Derived Antimony Complexes: Synthesis, Structural Analysis, and In Vitro Evaluation against Bacterial, Fungal, and Cancer Cells

Research Authors
Amany Fathy, Ahmed B.M. Ibrahim, S. Abd Elkhalik, Florian Meurer, Michael Bodensteiner, S.M. Abbas
Research Date
Research Department
Research Journal
Inorganics
Research Pages
172
Research Vol
10
Research Website
https://www.mdpi.com/2304-6740/10/10/172
Research Year
2022

Synthesis, X-ray structure and anticancer activity evaluation of a binuclear La(III) complex with anthranilic acid

Research Authors
Amna S.A. Zidan, Hanan K. Mosbah, Aref A.M. Aly, Ahmed B.M. Ibrahim, Peter Mayer, Saber H. Saber
Research Date
Research Department
Research Pages
1414-1423
Research Publisher
Natural Product Research
Research Vol
38(8)
Research Website
https://www.tandfonline.com/doi/abs/10.1080/14786419.2022.2148246?journalCode=gnpl20
Research Year
2024

(NH4)2[Co(H2O)6]2V10O28∙4H2O Vs. (NH4)2[Ni(H2O)6]2V10O28∙4H2O: structural, spectral and thermal analyses and evaluation of their antibacterial activities

Research Authors
Ayat-Allah Mamdouh, Ahmed B.M. Ibrahim, Nour El-Houda A. Reyad, Tarek R. Elsayed, Isabel Cordeiro Santos, António Paulo, Refaat M. Mahfouz,
Research Date
Research Department
Research Journal
Journal of Cluster Science
Research Pages
1535-1546
Research Vol
34
Research Website
https://link.springer.com/article/10.1007/s10876-022-02326-2
Research Year
2023

A new ultrasensitive platform based on f-GCNFs@nano-CeO2 core-shell nanocomposite for electrochemical sensing of oxidative stress biomarker 3-nitrotyrosine in presence of uric acid and tyrosine

Research Abstract
Research Authors
Hazim M.AliaIbrahimHotan AlsohaimiaA.A.NaylaAmr A.EssawyaMohammedGamalbHossienyIbrahimc
Research Date
Research Department
Research Year
2022

Tailoring the photoluminescence of capmatinib towards a novel ultrasensitive spectrofluorimetric and HPLC-DAD monitoring in human serum; investigation of the greenness characteristics

Research Abstract
Research Authors
Hazim M. AliAmr A. EssawyIbrahim Hotan AlsohaimiA.A. NaylHossieny IbrahimAbd El-Naby I. EssawyMohammed ElmowafyMohammed Gamal
Research Date
Research Department
Research Journal
Microchemical Journal
Research Pages
107838
Research Publisher
Elsevier
Research Rank
international
Research Vol
vol 181
Research Year
2022

Probabilistic seismic hazard assessment for Western Mexico

Research Abstract

An updated probabilistic seismic hazard analysis in terms of peak ground acceleration and spectral acceleration values, for B, B/C, and C NEHRP site classes, for a 5% and 10% probability of exceedance in 50 years, has been conducted for Western Mexico. To achieve this assessment, a unified and updated declustered earthquake catalog (1787–2019), as well as an updated focal mechanism database (1963–2016), was compiled, prepared, and processed specifically for this work. Two alternative source models (area sources and a spatially smoothed seismicity model) were considered in the assessment, within a logic tree scheme. A characteristic earthquake model has been also implemented for some of the defined sources. The designed logic tree has additionally included other parameters: the possible uncertainty related to the Gutenberg-Richter b-value way of estimation, the maximum expected magnitude value, as well as two-alternative GMPEs selected for the subduction seismic sources. The obtained ground-motion results have been presented as seismic hazard isoacceleration maps, as well as uniform hazard spectra and hazard curves for 15 selected cities, for the three considered site conditions. A comparison between the obtained hazard values and the current seismic design regulations, as well as previous studies, has been also performed, and a new design response spectrum has been proposed. Finally, some regression fitting relationships between the obtained ground-motion values have been achieved. Concerning the most significant results, it is worth noting that the southwestern coast (in the perimeter of the Middle America Trench of the Mexican Subduction Zone) presents the highest hazard values. For instance, the cities of Apatzingán, Autlán, Colima, Lázaro Cárdenas, and Manzanillo exhibit the largest observed PGA values among all the studied cities. Our approach and results are supported by the fact that the recent September 19, 2022, Mw 7.6 earthquake has been located in this highest seismic hazard area.

Research Authors
Rashad Sawires, José A. Peláez, Miguel A. Santoyo
Research Date
Research Department
Research Journal
Engineering Geology
Research Member
Research Pages
106959
Research Publisher
Elsevier
Research Rank
Q1
Research Vol
313
Research Website
https://www.sciencedirect.com/science/article/pii/S0013795222004446
Research Year
2023

Construction of Porous Organic/Inorganic Hybrid Polymers Based on Polyhedral Oligomeric Silsesquioxane for Energy Storage and Hydrogen Production from Water

Research Abstract

In this study, we used effective and one-pot Heck coupling reactions under moderate reaction conditions to construct two new hybrid porous polymers (named OVS-P-TPA and OVS-P-F HPPs) with high yield, based on silsesquioxane cage nanoparticles through the reaction of octavinylsilsesquioxane (OVS) with different brominated pyrene (P-Br4), triphenylamine (TPA-Br3), and fluorene (F-Br2) as co-monomer units. The successful syntheses of both OVS-HPPs were tested using various instruments, such as X-ray photoelectron (XPS), solid-state 13C NMR, and Fourier transform infrared spectroscopy (FTIR) analyses. All spectroscopic data confirmed the successful incorporation and linkage of P, TPA, and F units into the POSS cage in order to form porous OVS-HPP materials. In addition, the thermogravimetric analysis (TGA) and N2 adsorption analyses revealed the thermal stabilities of OVS-P-F HPP (Td10 = 444 °C; char yield: 79 wt%), with a significant specific surface area of 375 m2 g–1 and a large pore volume of 0.69 cm3 g–1. According to electrochemical three-electrode performance, the OVS-P-F HPP precursor displayed superior capacitances of 292 F g−1 with a capacity retention of 99.8% compared to OVS-P-TPA HPP material. Interestingly, the OVS-P-TPA HPP showed a promising HER value of 701.9 µmol g−1 h−1, which is more than 12 times higher than that of OVS-P-F HPP (56.6 µmol g−1 h−1), based on photocatalytic experimental results.

Research Authors
Mohamed Gamal Mohamed, Mohamed Hammad Elsayed, Yunsheng Ye, Maha Mohamed Samy, Ahmed E. Hassan, Tharwat Hassan Mansoure, Zhenhai Wen, Ho-Hsiu Chou, Kuei-Hsien Chen, and Shiao-Wei Kuo
Research Date
Research Department
Research Journal
Polymers
Research Pages
182-197
Research Publisher
MDPI
Research Vol
15
Research Website
https://www.mdpi.com/2073-4360/15/1/182
Research Year
2022

Constructing conjugated microporous polymers containing triphenylamine moieties for high-performance capacitive energy storage

Research Abstract

In this research we developed two triphenylamine (TPA)-linked conjugated microporous polymers (CMPs), TPA-TAB and TPA-TBN, through Suzuki couplings of tris(4-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)phenyl)amine (TPA-BO) with the aryl bromides tetrakis(4-bromophenyl)benzidine (TAB-Br4) and 2,7,10,15-tetrabromotetrabenzonaphthalene (TBN-Br4), respectively. These CMPs, which have substantial surface surfaces and outstanding thermal stability, could be employed as electrode materials in supercapacitor (SC) devices. In a three-electrode SC, the TPA-TAB CMP exhibited ultrahigh specific capacitance (684 F g−1 at 0.5 A g−1) and long-term stability, with a capacitance retention of 99.5% after 5000 cycles (at 10 A g−1). Moreover, a two-electrode symmetric SC incorporating TPA-TAB CMP presented a capacitance of 117 F g−1 and a high retention of 98% when subjected to 5000 cycles at 10 A g−1. This exceptional performance resulted from was achieved through the use of redox-active TPA units and a large BET surface area (490 m2 g−1). Accordingly, such TPA-CMPs appear to have promise for use in charge and energy storage applications.

Research Authors
Maha Mohamed Samy, Mohamed Gamal Mohamed, Santosh U. Sharma, Swetha V. Chaganti, Tharwat Hassan Mansoure, Jyh-Tsung Lee, Tao Chen, Shiao-Wei Kuo
Research Date
Research Department
Research Journal
Polymer
Research Pages
125541 - 125550
Research Publisher
ELSEVIER
Research Vol
264
Research Website
https://www.sciencedirect.com/science/article/pii/S0032386122010291
Research Year
2022
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