The ligand substitution reactions of dehydroacetic acid (Hdha) in [Fe(dha)3] with second ligand such as 8-hydroxyquinoline (Hquin), 1,4-
dihydroxyanthraquinone (H2dhaq) and 1,4,5,8-tetra-hydroxyanthraquinone (H4thaq) were investigated spectrophotometrically by in low polarity
solvents like benzene, chloroform and dichloromethane. It is deduced that the substitution reaction takes place through one successive step. The
reaction was performed at four different temperatures (5–25) ◦C, and it exhibits a first order dependence on the concentration of the starting
complex. The observed rate constant depends on the concentration of both leaving and entering ligands. The evaluation of the kinetic data
gives activation parameters which support an associative mechanism in the transition states and the higher rate of substitution of the dha in
Fe(dha)3 complex is due to entropy effect. The solid complexes were synthesized and characterized by elemental analysis, IR and UV–vis spectral
techniques.

Abstract

The present article embraces the photocatalytic previous termoxidationnext term (PCO) of three previous termselected cyclohexyl alcoholsnext term namely cyclohexylmethanol (1), 2-cyclohexylethanol (2) and 1-cyclohexylethanol (3) using previous termnanoparticlesnext term titanium dioxide (TiO2-P25) as a semiconductor photocatalyst in acetonitrile under aerated conditions. The photocatalytic experiments showed moderate conversion ratios (55.2%, 51.8% and 60.3%, respectively). The primary photocatalytic previous termoxidationnext term products are the corresponding aldehydes or ketones and acids. The photocatalytic previous termoxidationnext term products were identified mainly by GC and GC/MS techniques using authentic samples. Formation of electron–hole pair at the surface of the semiconductor previous termnanoparticlesnext term followed by previous termoxidationnext term reaction was the suggested mechanism. A first-order kinetic model was observed for the photocatalytic previous termoxidationnext term of the investigated previous termalcoholsnext term and the rate constants were calculated.

Abstract

The present article embraces the photocatalytic previous termoxidationnext term (PCO) of three previous termselected cyclohexyl alcoholsnext term namely cyclohexylmethanol (1), 2-cyclohexylethanol (2) and 1-cyclohexylethanol (3) using previous termnanoparticlesnext term titanium dioxide (TiO2-P25) as a semiconductor photocatalyst in acetonitrile under aerated conditions. The photocatalytic experiments showed moderate conversion ratios (55.2%, 51.8% and 60.3%, respectively). The primary photocatalytic previous termoxidationnext term products are the corresponding aldehydes or ketones and acids. The photocatalytic previous termoxidationnext term products were identified mainly by GC and GC/MS techniques using authentic samples. Formation of electron–hole pair at the surface of the semiconductor previous termnanoparticlesnext term followed by previous termoxidationnext term reaction was the suggested mechanism. A first-order kinetic model was observed for the photocatalytic previous termoxidationnext term of the investigated previous termalcoholsnext term and the rate constants were calculated.

Abstract

The present article embraces the photocatalytic previous termoxidationnext term (PCO) of three previous termselected cyclohexyl alcoholsnext term namely cyclohexylmethanol (1), 2-cyclohexylethanol (2) and 1-cyclohexylethanol (3) using previous termnanoparticlesnext term titanium dioxide (TiO2-P25) as a semiconductor photocatalyst in acetonitrile under aerated conditions. The photocatalytic experiments showed moderate conversion ratios (55.2%, 51.8% and 60.3%, respectively). The primary photocatalytic previous termoxidationnext term products are the corresponding aldehydes or ketones and acids. The photocatalytic previous termoxidationnext term products were identified mainly by GC and GC/MS techniques using authentic samples. Formation of electron–hole pair at the surface of the semiconductor previous termnanoparticlesnext term followed by previous termoxidationnext term reaction was the suggested mechanism. A first-order kinetic model was observed for the photocatalytic previous termoxidationnext term of the investigated previous termalcoholsnext term and the rate constants were calculated.

Abstract

The present article embraces the photocatalytic previous termoxidationnext term (PCO) of three previous termselected cyclohexyl alcoholsnext term namely cyclohexylmethanol (1), 2-cyclohexylethanol (2) and 1-cyclohexylethanol (3) using previous termnanoparticlesnext term titanium dioxide (TiO2-P25) as a semiconductor photocatalyst in acetonitrile under aerated conditions. The photocatalytic experiments showed moderate conversion ratios (55.2%, 51.8% and 60.3%, respectively). The primary photocatalytic previous termoxidationnext term products are the corresponding aldehydes or ketones and acids. The photocatalytic previous termoxidationnext term products were identified mainly by GC and GC/MS techniques using authentic samples. Formation of electron–hole pair at the surface of the semiconductor previous termnanoparticlesnext term followed by previous termoxidationnext term reaction was the suggested mechanism. A first-order kinetic model was observed for the photocatalytic previous termoxidationnext term of the investigated previous termalcoholsnext term and the rate constants were calculated.