The influence of Rb in the triple sulfate LiK(1−x)RbxSO4 (0 ≤ x ≤ 0.2) compound on the structural and thermal properties of the bulk material is discussed. Samples were prepared by fusing the sulfates in stoichiometric ratios in a platinum crucible at 1273 K for 30 min. The x-ray powder diffraction measurements were performed at ambient temperature. The crystal structure parameters were refined by the Rietveld method using the FullProf program. The analysis indicated a single-phase having a hexagonal symmetry with space group P63 regardless of the Rb content. Thermal analysis by differential scanning calorimetry shows a considerable shift of the phase transition point towards lower temperatures with increasing Rb content. A pre-transitional effect is observed by differential thermal analysis of the sample without Rb contribution while for the sample with 20% Rb the transition is represented by double endothermic peaks. The energy of transition has been estimated using the Kissinger method for samples with different concentrations of Rb

The kinetics of hardening precipitates of Al-1.12 wt.% Mg2Si-0.35 wt.% Si (excess Si) and Al-1.07 wt.% Mg2Si-0.33 wt.% Cu (balanced + Cu) alloys have been investigated by means of differential scanning calorimetry and hardness measurements. The excess Si enhances the precipitation kinetics and improves the strength of the material. On the other hand, however addition of Cu assist formation of the Q phase which positively changed the alloy strength. The high binding energy between vacancies and solute atoms (Si and Mg) enhances the combination of Si, Mg and vacancies to form Si-Mg-vacancy clusters. These clusters act as nucleation sites for GP-zones. The coexistence of the β'- and Q'-precipitates in the balanced + Cu alloy results in a higher peak age hardening compared to the alloy with Si in excess

The kinetics of hardening precipitates of Al-1.12 wt.% Mg2Si-0.35 wt.% Si (excess Si) and Al-1.07 wt.% Mg2Si-0.33 wt.% Cu (balanced + Cu) alloys have been investigated by means of differential scanning calorimetry and hardness measurements. The excess Si enhances the precipitation kinetics and improves the strength of the material. On the other hand, however addition of Cu assist formation of the Q phase which positively changed the alloy strength. The high binding energy between vacancies and solute atoms (Si and Mg) enhances the combination of Si, Mg and vacancies to form Si-Mg-vacancy clusters. These clusters act as nucleation sites for GP-zones. The coexistence of the β'- and Q'-precipitates in the balanced + Cu alloy results in a higher peak age hardening compared to the alloy with Si in excess

The kinetics of hardening precipitates of Al-1.12 wt.% Mg2Si-0.35 wt.% Si (excess Si) and Al-1.07 wt.% Mg2Si-0.33 wt.% Cu (balanced + Cu) alloys have been investigated by means of differential scanning calorimetry and hardness measurements. The excess Si enhances the precipitation kinetics and improves the strength of the material. On the other hand, however addition of Cu assist formation of the Q phase which positively changed the alloy strength. The high binding energy between vacancies and solute atoms (Si and Mg) enhances the combination of Si, Mg and vacancies to form Si-Mg-vacancy clusters. These clusters act as nucleation sites for GP-zones. The coexistence of the β'- and Q'-precipitates in the balanced + Cu alloy results in a higher peak age hardening compared to the alloy with Si in excess

The kinetics of hardening precipitates of Al-1.12 wt.% Mg2Si-0.35 wt.% Si (excess Si) and Al-1.07 wt.% Mg2Si-0.33 wt.% Cu (balanced + Cu) alloys have been investigated by means of differential scanning calorimetry and hardness measurements. The excess Si enhances the precipitation kinetics and improves the strength of the material. On the other hand, however addition of Cu assist formation of the Q phase which positively changed the alloy strength. The high binding energy between vacancies and solute atoms (Si and Mg) enhances the combination of Si, Mg and vacancies to form Si-Mg-vacancy clusters. These clusters act as nucleation sites for GP-zones. The coexistence of the β'- and Q'-precipitates in the balanced + Cu alloy results in a higher peak age hardening compared to the alloy with Si in excess

Polycrystalline LiK1-xRbxSO4 mixed crystals (with x=0.1 and 0.2) have been synthesized by air quenching of the melt and characterized by X-ray powder diffraction and DSC measurements. Their ionic conductivity has been measured as a function of temperature over a wide frequency range. From an analysis of the frequency-dependent conductivity at different temperatures below and above the reconstructive phase transition, the dc conductivity, the hopping frequency of mobile ions and the exponent n of the ac dispersive regime are determined. The values of the activation energy for the ac and dc conductivities and that of the hopping process are found to be almost the same, implying that the charge-carriers concentration is independent of temperature. The power-law exponent n of the conductivity spectra has average values of 0.57 and 0.66 in the room- and high-temperature phases, respectively, indicating different conduction properties in the two phases. Moreover, scaling of the conductivity spectra at the room- and high-temperature phases points to the structural influence on the microscopic dynamics of mobile ions

The dc conductivity (σ) along the polar b-axis of ammonium zinc chloride (AZC) crystals in its four hightemperature
phases has been measured as a function of temperature. Doping with Mn2+ in different
concentrations changed strongly both values of σ at all temperatures and the dependence of ln σdc on 1/T in
the phase transition regions. The activation energy of conduction was calculated from the linear portions of
this dependence in each phase. The results were discussed in the light of the decomposition of (NH4)2 in the
high-temperature normal phase, the discommensuaration (DC) formation/annihilation in the incommensurate
phase and domain wall motion and stripples nucleation in the commensurate- and antiferroelectric-phases.
Pinning of DC’s in the crystal lattice and/or by the structural defects and the possibility of dislocation
formation was also discussed. The bulk- and the electrode-limited conduction mechanisms were also
considered. The current density-voltage gradient relationship according to the usual Richardson-Schottky (RS)
equation shows disagreement between extracted parameters and experimentally measured ones. A
modified equation was used to solve this difficulty which, in addition, facilitated the calculation of the
electronic mobility (μ), the barrier height (ϕ) at the electrode-dielectric interface and the R-S constant (βRS).
The effect of Mn2+-content on values of μ, ϕ and βRS in different phases of AZC was also considered

The dc conductivity (σ) along the polar b-axis of ammonium zinc chloride (AZC) crystals in its four hightemperature
phases has been measured as a function of temperature. Doping with Mn2+ in different
concentrations changed strongly both values of σ at all temperatures and the dependence of ln σdc on 1/T in
the phase transition regions. The activation energy of conduction was calculated from the linear portions of
this dependence in each phase. The results were discussed in the light of the decomposition of (NH4)2 in the
high-temperature normal phase, the discommensuaration (DC) formation/annihilation in the incommensurate
phase and domain wall motion and stripples nucleation in the commensurate- and antiferroelectric-phases.
Pinning of DC’s in the crystal lattice and/or by the structural defects and the possibility of dislocation
formation was also discussed. The bulk- and the electrode-limited conduction mechanisms were also
considered. The current density-voltage gradient relationship according to the usual Richardson-Schottky (RS)
equation shows disagreement between extracted parameters and experimentally measured ones. A
modified equation was used to solve this difficulty which, in addition, facilitated the calculation of the
electronic mobility (μ), the barrier height (ϕ) at the electrode-dielectric interface and the R-S constant (βRS).
The effect of Mn2+-content on values of μ, ϕ and βRS in different phases of AZC was also considered

The effect of chemical non-stoichiometry and γ-irradiation on the unit cell parameters of ammonium
tetrachlorozincate (NH4)2ZnCl4 (A2ZC4) has been studied. The unit cell parameters of crystal grown from
solution with NH4Cl/ZnCl2 molar ratio 1:1, apparently non-stoichiometrric, are nearly the same as those given
for ammonium tetrachlorozincate in the literature. The 2:1 ratio is actually ‘pseudo-stoichiometric’ due to the
hygroscopic nature of ZnCl2. The unit cell parameters of crystal grown from solution with molar ratio 2:1
match those of the structure (NH4)3ZnCl5 (A3ZC5). The habit of the crystal grown in the former case, from
solution with excess ZnCl2, was different from that of the crystal grown in the later case, from solution with
excess (NH4)Cl. Between these two limits, a set of four samples were prepared from solutions with an excess
of ZnCl2 of 20, 30, 60 and 80 wt % in order to detect exact stoichiometric composition to grow A2ZC4.
Analysis by X-ray diffraction shows that the first two crystals out of this set are mixed from A2ZC4 and
A3ZC5 The third and fourth crystals still contain traces of A3ZC5. Analysis of the X-ray diffraction was then
confirmed by DTA study. Irradiating A2ZC4 with γ-dose of 250 kGy slightly increased the unit cell volume
due to imperfections created by irradiation. Two computer programs were used to calculate the lattice
constants and the results were compared

The effect of chemical non-stoichiometry and γ-irradiation on the unit cell parameters of ammonium
tetrachlorozincate (NH4)2ZnCl4 (A2ZC4) has been studied. The unit cell parameters of crystal grown from
solution with NH4Cl/ZnCl2 molar ratio 1:1, apparently non-stoichiometrric, are nearly the same as those given
for ammonium tetrachlorozincate in the literature. The 2:1 ratio is actually ‘pseudo-stoichiometric’ due to the
hygroscopic nature of ZnCl2. The unit cell parameters of crystal grown from solution with molar ratio 2:1
match those of the structure (NH4)3ZnCl5 (A3ZC5). The habit of the crystal grown in the former case, from
solution with excess ZnCl2, was different from that of the crystal grown in the later case, from solution with
excess (NH4)Cl. Between these two limits, a set of four samples were prepared from solutions with an excess
of ZnCl2 of 20, 30, 60 and 80 wt % in order to detect exact stoichiometric composition to grow A2ZC4.
Analysis by X-ray diffraction shows that the first two crystals out of this set are mixed from A2ZC4 and
A3ZC5 The third and fourth crystals still contain traces of A3ZC5. Analysis of the X-ray diffraction was then
confirmed by DTA study. Irradiating A2ZC4 with γ-dose of 250 kGy slightly increased the unit cell volume
due to imperfections created by irradiation. Two computer programs were used to calculate the lattice
constants and the results were compared