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Kinetic Studies of Thermal Degradation of the Reduced and Oxidized Poly(o-toluidine)

Research Abstract
Thermal degradation of poly(o-toluidine) (POT) reduced [base form (POT-EB)] and oxidized form [i.e. doped with salicylidine-aniline (SA) and/or salicylidine-o-aminophenol (SAP)] was investigated experimentally and computationally. The results of thermal (TGA) and differential thermal (DTG) gravimetric analysis suggest a higher thermal stability for the oxidized (SA or SAP-doped POT) than that for the respective reduced (POT-EB) chain. Nonisothermal degradation of the reduced POT matrix reveals hydrophilic nature about two times stronger than that for the oxidized form (SA and/or SAP-doped POT) under the same conditions. Molecular mechanics (MM/) calculations substantiate these observations. FTIR spectroscopic study of the calcined POT-EB showed that the quinoid (Q) ring (iminostructure) is thermally at least twice more stable than for that the benzenoid (B) rings (aminostructure) in the repeating unit of the polymer chain. Isothermal degradation curves [fraction decomposed (a) vs. degradation time (t in min)] of the polymers under investigation revealed that they are characteristically declaratory in shape.
Research Authors
S.M. Ahmed, B.M. Abu-Zied
Research Department
Research Journal
Journal of Analytical and Applied Pyrolysis
Research Pages
13
Research Publisher
Elsevier
Research Rank
1
Research Vol
, 70(2) (2003) 277-289
Research Website
NULL
Research Year
2003

Kinetic Studies of Thermal Degradation of the Reduced and Oxidized Poly(o-toluidine)

Research Abstract
Thermal degradation of poly(o-toluidine) (POT) reduced [base form (POT-EB)] and oxidized form [i.e. doped with salicylidine-aniline (SA) and/or salicylidine-o-aminophenol (SAP)] was investigated experimentally and computationally. The results of thermal (TGA) and differential thermal (DTG) gravimetric analysis suggest a higher thermal stability for the oxidized (SA or SAP-doped POT) than that for the respective reduced (POT-EB) chain. Nonisothermal degradation of the reduced POT matrix reveals hydrophilic nature about two times stronger than that for the oxidized form (SA and/or SAP-doped POT) under the same conditions. Molecular mechanics (MM/) calculations substantiate these observations. FTIR spectroscopic study of the calcined POT-EB showed that the quinoid (Q) ring (iminostructure) is thermally at least twice more stable than for that the benzenoid (B) rings (aminostructure) in the repeating unit of the polymer chain. Isothermal degradation curves [fraction decomposed (a) vs. degradation time (t in min)] of the polymers under investigation revealed that they are characteristically declaratory in shape.
Research Authors
S.M. Ahmed, B.M. Abu-Zied
Research Department
Research Journal
Journal of Analytical and Applied Pyrolysis
Research Pages
13
Research Publisher
Elsevier
Research Rank
1
Research Vol
, 70(2) (2003) 277-289
Research Website
NULL
Research Year
2003

intramuscular Cyclization of Mannich Reaction for Synthesis of pyrimido[2,1-b]- 1,3,5-tiadiazines

Research Authors
Hassan A. H. El-Sherief, Zeniab A. Hozien, Ahmed F. M. El-Mahdy, Abdelwareth A. O. Sarhan
Research Department
Research Journal
Heterocyclic Chemistry
Research Member
Abdel-wareth Abdel-Halim Othman Sarhan
Research Pages
PP. 1294-1302
Research Rank
1
Research Vol
Vol 47,
Research Year
2010

intramuscular Cyclization of Mannich Reaction for Synthesis of pyrimido[2,1-b]- 1,3,5-tiadiazines

Research Authors
Hassan A. H. El-Sherief, Zeniab A. Hozien, Ahmed F. M. El-Mahdy, Abdelwareth A. O. Sarhan
Research Department
Research Journal
Heterocyclic Chemistry
Research Pages
PP. 1294-1302
Research Rank
1
Research Vol
Vol 47,
Research Year
2010

intramuscular Cyclization of Mannich Reaction for Synthesis of pyrimido[2,1-b]- 1,3,5-tiadiazines

Research Authors
Hassan A. H. El-Sherief, Zeniab A. Hozien, Ahmed F. M. El-Mahdy, Abdelwareth A. O. Sarhan
Research Department
Research Journal
Heterocyclic Chemistry
Research Pages
PP. 1294-1302
Research Rank
1
Research Vol
Vol 47,
Research Year
2010

Neoproterozoic podiform chromitites in serpentinites of the
Abu Meriewa–Hagar Dungash district, Eastern Desert, Egypt:
Geotectonic implications and metamorphism

Research Abstract
Podiform chromitites hosted in serpentinites (after harzburgite and dunite) and talc-carbonate rocks from the Abu Meriewa–Hagar Dungash district (MHD), Eastern Desert of Egypt, together with metagabbros, pillow metavolcanics, and metasediments, form an ophiolitic mélange formed during the Neoproterozoic Pan-African Orogeny. The chromitites show massive, disseminated, and nodular textures. Chromite cores in chromitites have high and restricted ranges of Cr# (0.65–0.75) and Mg# (0.64–0.83), implying primary compositions not affected by metamorphism. Therefore, they are used as reliable indicators of parent magma composition and tectonic affinities of these highly metamorphosed rocks. On the contrary, the altered rims are high-Cr, low-Fe3+ spinel (rather than ferritchromit) enriched in Cr, Fe, and Mn, and depleted in Al and Mg (Cr# = 0.75–0.97, Mg# = 0.29–0.79), due to equilibration with interstitial silicates during regional metamorphism up to transitional greenschist–amphibolite facies at about 500–550°C. The primary chromite compositions suggest derivation from a high-Mg tholeiitic, to possibly boninitic, parental magma in a supra-subduction zone (arc–marginal basin) environment, similar to the spatially associated metavolcanic rocks. The MHD chromitites are most probably formed by melt–rock interaction mechanisms. The high Cr# of the investigated chromites suggests high degrees of partial melting of a depleted harzburgite source by interaction with primitive basaltic melt of deeper origin followed by mixing. Such Cr-rich chromites are common in chromitites from the Eastern Desert of Egypt, implying broad thermal anomalies, possibly linked to an important geodynamic feature of the Arabian–Nubian Shield (ANS) evolution. This could revive interest in models that involve asthenospheric uprise, related to plume interaction or most probably due to oblique convergence of arc terranes during early evolution of the ANS.
Research Authors
FAWZY F. ABU EL ELELA AND ESAM S. FARAHAT
Research Department
Research Journal
Island Arc
Research Pages
PP. 151–164
Research Rank
1
Research Vol
Vol. 19, Issue 1
Research Website
http://onlinelibrary.wiley.com/doi/10.1111/j.1440-1738.2009.00689.x/abstract
Research Year
2010

Novel Method for the Synthesis of s-Triazolo[3,4-b][1,3,4]thiadiazines

Research Abstract
The acid-promoted condensation of the triazole (I) with a variety of ketones results in formation of triazolothiadiazines (III) in good yields.
Research Authors
Hassan A. H. El-Sherief, Zeniab A. Hozien, Ahmed F. M. El-Mahdy, Abdelwareth A. O. Sarhan
Research Department
Research Journal
ChemInform
Research Rank
1
Research Vol
Vol. 41, Issue 48
Research Website
http://onlinelibrary.wiley.com/doi/10.1002/chin.201048161/full
Research Year
2010

Novel Method for the Synthesis of s-Triazolo[3,4-b][1,3,4]thiadiazines

Research Abstract
The acid-promoted condensation of the triazole (I) with a variety of ketones results in formation of triazolothiadiazines (III) in good yields.
Research Authors
Hassan A. H. El-Sherief, Zeniab A. Hozien, Ahmed F. M. El-Mahdy, Abdelwareth A. O. Sarhan
Research Department
Research Journal
ChemInform
Research Member
Abdel-wareth Abdel-Halim Othman Sarhan
Research Rank
1
Research Vol
Vol. 41, Issue 48
Research Website
http://onlinelibrary.wiley.com/doi/10.1002/chin.201048161/full
Research Year
2010

Novel Method for the Synthesis of s-Triazolo[3,4-b][1,3,4]thiadiazines

Research Abstract
The acid-promoted condensation of the triazole (I) with a variety of ketones results in formation of triazolothiadiazines (III) in good yields.
Research Authors
Hassan A. H. El-Sherief, Zeniab A. Hozien, Ahmed F. M. El-Mahdy, Abdelwareth A. O. Sarhan
Research Department
Research Journal
ChemInform
Research Rank
1
Research Vol
Vol. 41, Issue 48
Research Website
http://onlinelibrary.wiley.com/doi/10.1002/chin.201048161/full
Research Year
2010
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