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Deposition of Ni(OH)2 on nickel substrate using vacuum kinetic spray and its application to high-performance supercapacitor

Research Abstract

Herein, we report a direct deposition of nano-structured Ni(OH)2 from micro-sized Ni(OH)2 powder on nickel sheet and nickel foam using nano-particle deposition system, one of the low-vacuum and room temperature vacuum kinetic spray processes. In this work, the deposition of the Ni(OH)2 powder on nickel sheets is carried out with various stand-off-distances (SoDs) and carrier gas pressures. The deposited films are investigated by field-emission electron microscopy, X-ray diffraction, and Raman spectroscopy. The crystallite size of the nano-structured Ni(OH)2 depends on the SoD and the carrier gas pressure. The electrochemical performance of Ni(OH)2 deposited on nickel sheets is measured by cyclic voltammetry in the 3-electrode cell. The deposition with 5 mm SoD and 0.3 MPa carrier gas pressure is found to be the optimum deposition condition for the nano-structured Ni(OH)2 thin film as an electrode material. The nano-structured Ni(OH)2 thin film deposited with 5 mm SoD and 0.3 MPa carrier gas pressure on nickel foam demonstrates a specific capacitance of 2377 F g−1 at 2 mV s−1 scan rate and 2092 F g−1 at 1 A g−1 current density and excellent cyclic stability for 3000 cycles with 83% capacitance retention.

Research Authors
Mohaned Mohammed Mahmoud Mohammed and Chun Doo-Man
Research Department
Research Journal
Journal of Materials Science: Materials in Electronics
Research Pages
17481–17490
Research Publisher
Springer
Research Rank
1
Research Vol
30
Research Website
https://doi.org/10.1007/s10854-019-02098-y
Research Year
2019

All-Solid-State Supercapacitor Based on MoS2–Graphite Composite Prepared by the Vacuum Kinetic Spray Method

Research Abstract

The combination of the molybdenum disulfide (MoS2) and graphite can result in very promising hybrid electrode material for use in energy storage devices owing to the interesting properties of the combined material, such as an extremely high surface area, and prominent electrical conductivity. In this study, MoS2 powder and graphite powder are mixed with different compositions via the ball milling. A nanoparticle deposition system is used to deposit MoS2–graphite composites on stainless-steel. The morphology and structure of the thin films are evaluated by field-emission scanning electron microscope, x-ray diffraction, and Raman spectroscopy. The electrochemical performances of supercapacitors fabricated from MoS2–graphite thin films as an electrode material using a two-electrode cell were evaluated by cyclic voltammetry, galvanostatic charge/discharge, and electrochemical impedance spectroscopy. The supercapacitor shows better performance at 15% of the MoS2–graphite composition ratio. Moreover, the cyclic stability of the supercapacitor is measured by repeating charging–discharging for 10,000 cycles.

Research Authors
Mohaned Mohammed Mahmoud Mohammed and Doo-Man Chun
Research Department
Research Journal
Journal of Thermal Spray Technology
Research Pages
963-973
Research Publisher
Springer
Research Rank
1
Research Vol
28
Research Website
https://doi.org/10.1007/s11666-019-00875-z
Research Year
2019

SYNTHESIS AND OPTICAL PROPERTIES OF CDSE/CDS CORE/SHELL NANOCRYSTALS

Research Abstract

NULL

Research Authors
A. GADALLA , M. S. ABD EL-SADEK , R. HAMOODA
Research Department
Research Journal
Journal of Material Science Poland, Springer
Research Pages
pp. 149-157
Research Publisher
NULL
Research Rank
1
Research Vol
Vol. 37 - No. 2
Research Website
NULL
Research Year
2019

Liquid crystalline polymers XVI*. Thermotropic liquid crystalline copoly(arylidene-ether)/TiO2 Nanocomposites: synthesis, characterisation and applications

Research Abstract

NULL

Research Authors
Kamal I Aly, Nayef S Al-Muaikel, Mona A Abdel-Rahman, Amal H Tolba
Research Department
Research Journal
Liquid Crystals
Research Member
Research Pages
pp. 1734-1746
Research Publisher
NULL
Research Rank
1
Research Vol
Vol. 46
Research Website
NULL
Research Year
2019

Liquid crystalline polymers XVI*. Thermotropic liquid crystalline copoly(arylidene-ether)/TiO2 Nanocomposites: synthesis, characterisation and applications

Research Abstract

NULL

Research Authors
Kamal I Aly, Nayef S Al-Muaikel, Mona A Abdel-Rahman, Amal H Tolba
Research Department
Research Journal
Liquid Crystals
Research Member
Research Pages
pp. 1734-1746
Research Publisher
NULL
Research Rank
1
Research Vol
Vol. 46
Research Website
NULL
Research Year
2019

Liquid crystalline polymers XVI*. Thermotropic liquid crystalline copoly(arylidene-ether)/TiO2 Nanocomposites: synthesis, characterisation and applications

Research Abstract

NULL

Research Authors
Kamal I Aly, Nayef S Al-Muaikel, Mona A Abdel-Rahman, Amal H Tolba
Research Department
Research Journal
Liquid Crystals
Research Member
Research Pages
pp. 1734-1746
Research Publisher
NULL
Research Rank
1
Research Vol
Vol. 46
Research Website
NULL
Research Year
2019

Conducting copolymers nanocomposite coatings with aggregation-controlled luminescence and efficient corrosion inhibition properties

Research Abstract

Luminescent coatings may provide low-cost techniques for studying the corrosion mechanism of coatings and for getting an early indication of corrosion processes. Here, a series of conducting copolymers and their nanocomposites has been synthesized and the effect of adding bulky moieties and/or nanocomposite formation on the solubility, thermal stability, corrosion inhibition, and photoluminescence of these copolymer coatings has been investigated. A significant enhancement in both solubility and thermal stability of the copolymers has been demonstrated upon the nanocomposite formation or presence of bulky groups. The nanocomposites displayed an inhibition efficiency of 97% for mild steel corrosion in an acidic environment which is much higher than that of the corresponding copolymers. Interestingly, the as-prepared copolymers and nanocomposites with tert-butyl group displayed an aggregation

Research Authors
Kamal I Aly, Osama Younis, Mahmoud H Mahross, Esam A Orabi, Mohamed Abdel-Hakim, Osamu Tsutsumi, Mohamed Gamal Mohamed, Marwa M Sayed
Research Department
Research Journal
Progress in Organic Coatings
Research Member
Mohamed Jamal El-Din Mohamed Abo El-Seoud
Research Pages
pp. 525-535
Research Publisher
NULL
Research Rank
1
Research Vol
Vol. 135
Research Website
NULL
Research Year
2019

Conducting copolymers nanocomposite coatings with aggregation-controlled luminescence and efficient corrosion inhibition properties

Research Abstract

Luminescent coatings may provide low-cost techniques for studying the corrosion mechanism of coatings and for getting an early indication of corrosion processes. Here, a series of conducting copolymers and their nanocomposites has been synthesized and the effect of adding bulky moieties and/or nanocomposite formation on the solubility, thermal stability, corrosion inhibition, and photoluminescence of these copolymer coatings has been investigated. A significant enhancement in both solubility and thermal stability of the copolymers has been demonstrated upon the nanocomposite formation or presence of bulky groups. The nanocomposites displayed an inhibition efficiency of 97% for mild steel corrosion in an acidic environment which is much higher than that of the corresponding copolymers. Interestingly, the as-prepared copolymers and nanocomposites with tert-butyl group displayed an aggregation

Research Authors
Kamal I Aly, Osama Younis, Mahmoud H Mahross, Esam A Orabi, Mohamed Abdel-Hakim, Osamu Tsutsumi, Mohamed Gamal Mohamed, Marwa M Sayed
Research Department
Research Journal
Progress in Organic Coatings
Research Member
Research Pages
pp. 525-535
Research Publisher
NULL
Research Rank
1
Research Vol
Vol. 135
Research Website
NULL
Research Year
2019

Diastereoselective synthesis of atropisomeric
pyrazolyl pyrrolo[3,4-d]isoxazolidines via pyrazolyl
nitrone cycloaddition to facially divergent
maleimides: intensive NMR and DFT studies

Research Abstract

NULL

Research Authors
Awad I. Said and Talaat I. El-Emary
Research Department
Research Journal
RSC Advances
Research Member
Research Pages
pp. 845-850
Research Publisher
NULL
Research Rank
1
Research Vol
Vol. 10 - No. 2
Research Website
NULL
Research Year
2020

Diastereoselective synthesis of atropisomeric
pyrazolyl pyrrolo[3,4-d]isoxazolidines via pyrazolyl
nitrone cycloaddition to facially divergent
maleimides: intensive NMR and DFT studies

Research Abstract

NULL

Research Authors
Awad I. Said and Talaat I. El-Emary
Research Department
Research Journal
RSC Advances
Research Member
Research Pages
pp. 845-850
Research Publisher
NULL
Research Rank
1
Research Vol
Vol. 10 - No. 2
Research Website
NULL
Research Year
2020
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