Pharmaceutical active compounds such as diclofenac (DCF) pose serious risks to aquatic ecosystems. Therefore,
the development of safe and inexpensive phytoremediation strategies is essential. This study assessed the effect of
foliar-applied biological gibberellin (BG; 0, 50, 100, and 150 mg L􀀀 1), produced by Fusarium proliferatum, on the
remediation capacity of Atriplex lentiformis halophyte grown hydroponically under DCF contamination (0, 15,
and 30 μg L􀀀 1). A. lentiformis effectively removed DCF from the medium, while BG implementation further
boosted the DCF removal efficiency, bioaccumulation, and translocation factors. The application of 150 mg L􀀀 1
BG to 30 μg L􀀀 1 DCF achieved up to 80 % DCF removal and the maximum accumulation of DCF by 154.8 % over
the control. BG also promoted plant growth and photosynthetic pigments while mitigating DCF toxicity by
enhancing non-enzymatic antioxidants (AsA, GSH, phenolics, and proline) and antioxidant enzymes (APX, GPX,
PPO, GR, and PAL), and reducing stress biomarkers (MDA, H2O2, and electrolyte leakage). BG treatments
modified protein patterns and induced new isozyme profiles, reflecting a strengthened antioxidant system.
Overall, BG is a promising solution that serves as an eco-friendly biostimulant to enhance phytoremediation
efficiency. Extending this approach to soil systems may provide a sustainable strategy for managing pharmaceutical
pollution.

Preparation of cobalt(II) and zinc(II) complexes with an asymmetric thiourea ligand, N-phenylpiperidine-1-
carbothioamide, (L), was achieved. The composition and structure of the complexes, [CoL2Cl2] (1) and [ZnL2Cl2]
(2), were determined using various techniques, including single-crystal X-ray diffraction. X-ray structural
analysis revealed a distorted tetrahedral arrangement in the vicinity of the central metal atoms, with coordination
involving two thioamide (L) ligands through their sulfur atoms and two chlorido ligands. Fusarium oxysporum
is one of the most damaging phytopathogens, causing substantial economic losses. Excessive application
of commercial antifungals promotes microbial resistance, making the search for new agents essential. The
bioactivity of the free ligand, the starting metal(II) chlorides, and complexes 1 and 2 (0–200 μg/ml) against
Fusarium oxysporum was evaluated, alongside Cycloheximide as a standard. All compounds exhibited higher
activities than the standard. The complexes were the most effective anti-Fusarium oxysporum agents, with the
highest inhibitions of 46 and 37 mm for 1, and 2, respectively. Experiments on the fungal pathogenicity of wheat
seeds indicated complete inhibition by complex 1 (pathogenicity = zero %), while pathogenicity was only 6.7 %
with complex 2. The phytotoxicity of these compounds was assessed based on the percentage of wheat germination
obtained. Complex 2 demonstrated the best results, being non-toxic to wheat seeds up to 100 μg/ml, but
its phytotoxicity at 200 μg/ml resulted in only 73 % wheat germination.

Detailed field and stratigraphic studies were undertaken on the Upper Cretaceous-lower Paleogene (K-Pg) pre-rift sequences at the Duwi Mountain Range (DMR), Quseir Area, Red Sea Coast, Egypt. Six stratigraphic sections were investigated to cover the
DMR. They are arranged in a south-north profile as follows: Gabal Hamadat, Nasser Mine, Beida Mine, Gabal Anz, Gabal Nakheil and
Wadi Sudmeen. The studied pre-rift (Red Sea Rift) succession is lithostratigraphically represented by the Duwi (uppermost part), Dakhla,
Tarawan, Esna, and Thebes (lowermost part) formations. Biostratigraphically, twenty-one global planktonic foraminiferal zones were
defined. Three syn-sedimentary tectonic events were recorded, the first and second tectonic events (TE I and TE II) were regional and lie
within the Duwi/Dakhla and the uppermost part of the Hamama Member. The TE I occurred at the Campanian/Maastrichtian (C/M) boundary, whereas the TE II occurred at the beginning of the Danian. TE III was local and is recorded only at Wadi Sudmeen within the Beida
Member in the latest Danian. These events were related to the Syrian-Arc Event, which caused the uplift of the DMR as paleo-highs during
this interval.

Magnesium alloys are considered promising candidates for industrial applications due to their mechanical properties and surface tailoring capability. However, magnesium alloys need wettability control because of their low surface energy and rapid oxide layer formation. Additionally, they exhibit poor corrosion resistance and corrode rapidly in chloride environments, causing pitting and structural degradation. Laser surface texturing is one of the unique processes to modify the surface morphology and surface modification of AZ31 Mg alloy. However, the precise control of laser texturing along with chemical surface treatment parameters to tailor the wettability and corrosion behavior of Mg alloys is still a challenge. This study aims to explore the post-treatment strategies for surface modification and the impact of each treatment on surface chemistry, surface morphology, and electrochemical behavior of AZ31 Mg alloy and wettability and corrosion behavior, simultaneously. This multi-step laser/hot water/silicone oil heat treatment surface engineering strategy enabled the surface tunability from hydrophilic (contact angle ≈ 88°) to superhydrophobic (≈ 178°) and significantly reduced the corrosion current density by up to 120 times lower as compared to flat Mg surface while increasing the charge transfer resistance by 30 folds. This facile surface engineering approach can open new pathways for targeted corrosion applications in industrial as well as healthcare applications.

Formaldehyde serves as a key intermediate in numerous industrial processes, leading to a steadily increasing global demand. Consequently, efficient methods for producing both clean hydrogen and water-free formaldehyde are of growing importance. However, a significant hurdle in catalysis remains the selection of materials that can enhance both stability and catalytic performance. So, in this article, we reported zirconium molybdate material (Z₁U₅ catalyst) as an active, stable, and selective catalyst for the conversion of methanol to formaldehyde. The catalysts were fabricated by hydrothermal method using various ratios of urea. Using TGA, DSC, XRD, FT-IR, SEM, HR-TEM, XPS, N₂ sorption analysis, and pyridine-TPD, the produced catalysts' structural, morphological, textural, and acidic properties have been analyzed. The catalyst with the highest performance was developed by optimizing several synthesis parameters, including the molar ratio of zirconium to urea, hydrothermal treatment temperature and duration, as well as the annealing temperature. Under the ideal conditions, the catalyst with a Zr:urea ratio of 1:5 (referred to as Z₁U₅) demonstrated the best activity, achieving a 98 % methanol conversion and 95 % selectivity toward formaldehyde at 300 °C. This outstanding catalytic behavior is ascribed to the presence of Brønsted acid sites of both weak and moderate strength on the catalyst surface. Moreover, the Z₁U₅ catalyst exhibited excellent long-term durability, maintaining consistent conversion and selectivity over a continuous 160 h operation.

CeO₂–Fe₂O₃ binary oxides were effectively incorporated into mesoporous spherical silica (MCM-41) via a sol–gel technique. The resultant CFO/MCM-41 nanocomposites, with metal loadings ranging from 3 to 30 wt%, were subsequently calcined at 550 °C and assessed as catalysts for the gas-phase dehydration of isobutyl alcohol. Structural and surface analyses using XRD, TG-DTA, ATR-FTIR, BET, TEM, EDX, XPS, and pyridine-adsorbed FTIR confirmed the formation of thermally stable, well-dispersed active phases, as well as the presence of both Lewis and Brønsted acid sites. The differences in catalytic activity among these nanocomposites were closely linked to variations in their acidity. Among all the catalysts, the 10 wt% CeFeO₃/MCM-41 sample demonstrated the best performance at 350 °C, achieving approximately 92 % isobutanol conversion, 100 % selectivity toward isobutylene, and a butene production rate of 45.10 mmol g⁻¹ h⁻¹ . The catalyst also showed excellent stability across five reuse cycles. The outstanding catalytic performance and stability were directly correlated with the material's enhanced structural integrity and optimized textural properties. Furthermore, XPS analysis revealed that the Ce^3 +/Ce⁴⁺ and Fe²⁺/Fe³⁺ redox states, modulated by Ce–Fe interactions, played a crucial role in tuning the catalyst’s acidity and catalytic performance.

It is aimed in this work to explore the possibility of using the reed stalks for the production of pulp suitable for papermaking. To attain this goal, chemical kraft pulping followed by a number of bleaching sequences was implemented. We bleached a reed kraft pulp using H₁H₂, D₀EOD₁ and ZEOD sequences (where H, D, EO and Z represent hypochlorite, chlorine-dioxide, alkaline extraction, and ozone respectively) to attain considerably good quality pulp that boosts the brightness and brings high mechanical strength. The elementary chlorine-free (ECF) light bleaching sequences (ZEOD) include an ozone stage which results in imparting a pulp quality to be better than the conventional ECF procedure (D₀EOD₁) and (H₁H₂). Furthermore, to determine the optical, physical, and mechanical properties of reed pulp and paper, the impact of filler retention regarding the properties of paper that incorporates fibers from nano-filler (CaCO₃) loading was investigated and compared with the conventional filler loading. The same amount of nano calcium carbonate additive helps impart optical and mechanical properties compared against the paper manufactured by conventional calcium carbonate.