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Innovations in hydrogen storage materials Synthesis, applications, and prospects

Research Abstract

Hydrogen, globally recognized as the most efficient and clean energy carrier, holds the potential to transform future energy systems through its use as a fuel and chemical resource. Although progress has been made in reversible hydrogen adsorption and release, challenges in storage continue to impede widespread adoption. This review explores recent advancements in hydrogen storage materials and synthesis methods, emphasizing the role of nanotechnology and innovative synthesis techniques in enhancing storage performance and addressing these challenges to drive progress in the field. The review provides a comprehensive overview of various material classes, including metal hydrides, complex hydrides, carbon materials, metal-organic frameworks (MOFs), and porous materials. Over 60 % of reviewed studies focused on metal hydrides and alloys for hydrogen storage. Additionally, the impact of nanotechnology on storage performance and the importance of optimizing synthesis parameters to tailor material properties for specific applications are summarized. Various synthesis methods are evaluated, with a special emphasis on the role of nanotechnology in improving storage performance. Mechanical milling emerges as a commonly used and cost-effective method for fabricating intermetallic hydrides capable of adjusting hydrogen storage properties. The review also explores hydrogen storage tank embrittlement mecha­ nisms, particularly subcritical crack growth, and examines the advantages and limitations of different materials for various applications, supported by case studies showcasing real-world implementations. The challenges underscore current limitations in hydrogen storage materials, highlighting the need for improved storage ca­ pacity and kinetics. The review also explores prospects for developing materials with enhanced performance and safety, providing a roadmap for ongoing advancements in the field. Key findings and directions for future research in hydrogen storage materials emphasize their critical role in shaping future energy systems.
 

Research Authors
Ahmed I. Osman, Ali Ayati, Mahmoud Farrokhi, Sara Khadempir, Amin Reza Rajabzadeh, Mohamed Farghali, Pavel Krivoshapkin, Bahareh Tanhaei, David W. Rooney, Pow-Seng Yap
Research Date
Research Department
Research Journal
Journal of Energy Storage
Research Pages
112376
Research Publisher
Elseiver
Research Rank
Q1
Research Vol
95
Research Year
2024

Enhanced hydrogen storage efficiency with sorbents and machine learning: a review

Research Abstract

Hydrogen is viewed as the future carbon–neutral fuel, yet hydrogen storage is a key issue for developing the hydrogen economy because current storage techniques are expensive and potentially unsafe due to pressures reaching up to 700 bar. As a consequence, research has recently designed advanced hydrogen sorbents, such as metal–organic frameworks, covalent organic frameworks, porous carbon-based adsorbents, zeolite, and advanced composites, for safer hydrogen storage. Here, we review hydrogen storage with a focus on hydrogen sources and production, advanced sorbents, and machine learning. Carbon-based sorbents include graphene, fullerene, carbon nanotubes and activated carbon. We observed that storage capacities reach up to 10 wt.% for metal–organic frameworks, 6 wt.% for covalent organic frameworks, and 3–5 wt.% for porous carbon-based adsorbents. High-entropy alloys and advanced composites exhibit improved stability and hydrogen uptake. Machine learning has allowed predicting efficient storage materials.
 

Research Authors
Ahmed I. Osman· Walaa Abd‑Elaziem· Mahmoud Nasr· Mohamed Farghali· Ahmed K. Rashwan· Atef Hamada· Y. Morris Wang· Moustafa A. Darwish10 · Tamer A. Sebaey. Khatab, Ammar H. Elsheikh
Research Date
Research Department
Research Journal
Environmental Chemistry Letters
Research Pages
1703–1740
Research Publisher
Springer
Research Rank
Q1
Research Vol
22
Research Year
2024

Conversion of waste into sustainable construction materials: A review of recent developments and prospects

Research Abstract

The production and use of traditional building materials contribute to environmental pollution and natural resource depletion. Besides, disposal of agricultural, industrial, and construction waste and other solid wastes is a significant contemporary for both developing and developed countries. Consequently, this study comprehensively examines sustainable construction materials (SCMs) sourced from waste materials. It analyzes 190 peerreviewed papers, evaluating their properties, engineering suitability, and their impacts on the environment, economy, and society. Findings reveal that most SCMs have good engineering performance, yet improvements are needed in demonstrating their environmental (33.3%), economic (40%), and social sustainability (73.3%). Also, most SCMs are in experimental stages, requiring further research on human toxicity, long-term savings, maintenance costs, and other vital indicators. This review highlights some of the current challenges facing SCMs to promote their further studies, reduce non-renewable energy consumption and solid waste recycling, and facilitate their application in green buildings.
 

Research Authors
Lin Chen, Mingyu Yang, Zhonghao Chen, Zhuolin Xie, Lepeng Huang, Ahmed I. Osman, Mohamed Farghali, Malindu Sandanayake, Engui Liu, Yong Han Ahn, Ala’a H. Al-Muhtaseb, David W. Rooney, Pow-Seng Yap
Research Date
Research Department
Research Journal
Materials Today Sustainability
Research Pages
100930
Research Publisher
Elsevier
Research Rank
Q1
Research Vol
27
Research Year
2024

Advancements in Solid Oxide Fuel Cell Technology: Bridging Performance Gaps for Enhanced Environmental Sustainability

Research Abstract

In light of the anticipated 50% increase in global energy demand by 2050, the demand for innovative, environmentally conscious, efficient, and dependable energy technologies is paramount. Solid oxide fuel cells (SOFCs) offer a promising solution for sustainable energy production. This comprehensive review provides a detailed analysis of SOFCs, covering their fundamentals, materials, performance, and diverse applications, while also addressing technological challenges and future prospects. The review emphasizes the key advantages of SOFCs, including their high efficiency of up to 60% and minimal environmental impact. It explores the significance of impurity resistance and durability in materials and manufacturing processes for SOFC components. Comparative evaluations demonstrate the superior energy efficiency and ecological effects of SOFCs compared to other fuel cell technologies. SOFCs’ versatility and potential are showcased through their applications in transportation, power generation and storage, portable devices, and residential usage. However, challenges such as cost, longevity, reliability, and integration with other energy systems are identified, emphasizing the need for supportive policies and regulations.
 

Research Authors
Jingjing Li, Junhan Cheng, Yubing Zhang, Zhonghao Chen, Mahmoud Nasr,* Mohamed Farghali, David W. Rooney, Pow-Seng Yap,* and Ahmed I. Osman
Research Date
Research Department
Research Journal
Advanced Energy and Sustainability Research
Research Pages
2400132
Research Publisher
Wiely
Research Rank
Q2
Research Vol
5
Research Year
2024

Advances in hydrogen storage materials: harnessing innovative technology, from machine learning to computational chemistry, for energy storage solutions

Research Abstract

The demand for clean and sustainable energy solutions is escalating as the global population grows and economies develop. Fossil fuels, which currently dominate the energy sector, contribute to greenhouse gas emissions and environmental degradation. In response to these challenges, hydrogen storage technologies have emerged as a promising avenue for achieving energy sustainability. This review provides an overview of recent advancements in hydrogen storage materials and technologies, emphasizing the importance of efficient storage for maximizing hydrogen's potential. The review highlights physical storage methods such as compressed hydrogen (reaching pressures of up to 70 MPa) and material-based approaches utilizing metal hydrides and carbon-containing substances. It also explores design considerations, computational chemistry, high-throughput screening, and machine-learning techniques employed in developing efficient hydrogen storage materials. This comprehensive analysis showcases the potential of hydrogen storage in addressing energy demands, reducing greenhouse gas emissions, and driving clean energy innovation.

Research Authors
Ahmed I. Osman a , Mahmoud Nasr b , Abdelazeem S. Eltaweil c , Mohamed Hosny d , Mohamed Farghali , Ahmed S. Al-Fatesh, David W. Rooney Eman M. Abd El-Monaem
Research Date
Research Department
Research Journal
International Journal of Hydrogen Energy
Research Pages
1270-1294
Research Publisher
Elsevier
Research Rank
Q1
Research Vol
167
Research Website
https://www.sciencedirect.com/science/article/pii/S036031992401053X
Research Year
2024

Molecular detection of bovine viral diarrhea virus in whole blood and oral swabs in cattle and buffaloes

Research Abstract

Bovine viral diarrhea (BVD), a common viral disease, can affect large ruminants, both domesticated and wild. In Assiut Governorate, there is little information about BVD despite their financial losses. Thus, the aim of this investigation was to study the current situation of BVDV infection among large ruminants in Assiut Governorate. In this study, 39 cattle and 11 buffaloes were obtained from various villages in the Assiut Governorate, Egypt. Whole blood and oral lesions swabs were collected for laboratory investigation using RT-PCR. Nine cattle and one buffalo were found to have BVDV-RNA. The clinical findings accompanied by BVDV infection in examined animals were fully discussed. The species, age, and sex of the animals that underwent molecular testing had no significant effect on the BVDV infection rate (P<0.05). Meanwhile, Assiut Governorate's climatic conditions were found to have a significant influence (P<0.001) on the BVD infection rate, in which the prevalence of BVDV infection was highest in the summer season. Emphasizing the importance of putting effective prevention and control measures in place throughout Egypt is recommended in order to minimize the prevalence of BVDV.

Research Authors
1- Fatma E. Mahran, Khaled A.S. El-Khabaz, Osama A. Ali and Zainab M.A. Youssef
Research Date
Research Department
Research File
BVD 2025.pdf (407.44 KB)
Research Journal
Assiut Veterinary Medical Journal
Research Pages
459-567
Research Publisher
Zeinab Mohammed Ahmed Mohammed
Research Vol
71
Research Year
2025

Protective and therapeutic effects of empagliflozin in nephrotoxicity induced by 5-Fluorouracil in rats: Role of caspase-3, inflammation and oxidative stress

Research Abstract

Empagliflozin (EMPA) is a glucose-lowering agent that is widely used for treatment of diabetes mellitus and diabetic nephropathy. This work aimed to evaluate the therapeutic and prophylactic effects of EMPA and NAC in treating nephrotoxicity caused by 5-Fluorouracil (5-FU) in male Albino Wistar rats. 48 rats were divided into 6 groups: The first group used as negative control. The second received 20 mg/kg of 5-FU intraperitoneally for 6 days. The third group received 5-FU plus 10 mg/kg EMPA orally for 10 days. The fourth group received EMPA 10 days before the injection of 5-FU. The fifth group received 5-FU plus N-acetylcysteine (NAC) 40 mg/kg. The sixth group received 5-FU, NAC plus EMPA. Biochemical evaluation for urea, creatinine, uric acid, albumin, TNF-α and IL-1β in serum and GSH and MDA in renal homogenate were done. Histopathological examination of kidneys was done with immunohistochemical analysis of caspase-3. The nephrotoxic effect of 5-FU was characterized by elevation of creatinine, urea, uric acid, MDA, TNF-α and IL-1β with reduction of albumin and GSH. EMPA caused improvement in kidney status especially when used therapeutically or with NAC. The immunohistochemical analysis showed that EMPA caused a reduction in the expression of caspase-3. EMPA is an effective drug in cases of 5-FU induced nephrotoxicity. It is more effective when used as a treatment rather than a prophylactic strategy. The effect of EMPA is enhanced when combined with NAC. EMPA nephroprotective effect is mediated via antioxidant, antiinflammatory effects and by decreasing the expression of renal caspase-3.

Research Authors
Mohamed M. Elbadr, Sabah. M. Mohamed, Khaled M. A. Hassanein, Hala M. ElBadre, Ebtsam S. Abdel-lah, Esraa A. Ahmed1
Research Date
Research Department
Research Journal
Journal of Advanced Veterinary Research
Research Pages
1201-1207
Research Rank
International
Research Vol
14(7)
Research Year
2024
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