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New Unsaturated Copolyesters based on
Diarylidenecyclopentanone. Optimum conditions of
Synthesis, Characterization and Morphology.

Research Abstract

A new interesting series of linear, unsaturated copolyesters containing
cyclopentanone moiety in the main chain were synthesized by interfacial
polycondensation of a mixture containing one mole of both monomeric units 2,5-bis
(4-hydroxybenzylidene) cyclopentanone (Ia) and 2,5-bis (4-hydroxy-3-
methoxybenzylidene) cyclopentanone (Ib) together with two moles of different acid
chlorides. The yield and the values of reduced viscosity of the copolyesters were
found to be affected by the kind of organic phase, contribution of
benzyltriethylammonium chloride as a catalyst, the quantitative ratio of organic to
aqueous phase, concentration of hydrogen chloride acceptor and time of addition of
the acid chloride. The resulting copolyesters were characterized by elemental and
spectral analyses. Moreover, the various characteristics of the various types of
prepared copolymers including: solubility, viscosity, X-ray diffraction analysis, DSC
and TGA were determined and discussed. The electrical properties of the copolyesters
were tested and the morphology of selected examples of the copolyesters was
examined by scanning electron microscopy.

Research Authors
Kamal I. Aly, Ahmed S. Hammam, Shaban M. Radwan, and Mona A. Abdel-Rahman
Research Department
Research Journal
International Journal of Basic & Applied Sciences IJBAS-IJENS
Research Member
Research Pages
PP.15-35
Research Rank
1
Research Vol
Vol: 11 No: 04
Research Year
2011

New Unsaturated Copolyesters based on
Diarylidenecyclopentanone. Optimum conditions of
Synthesis, Characterization and Morphology.

Research Abstract

A new interesting series of linear, unsaturated copolyesters containing
cyclopentanone moiety in the main chain were synthesized by interfacial
polycondensation of a mixture containing one mole of both monomeric units 2,5-bis
(4-hydroxybenzylidene) cyclopentanone (Ia) and 2,5-bis (4-hydroxy-3-
methoxybenzylidene) cyclopentanone (Ib) together with two moles of different acid
chlorides. The yield and the values of reduced viscosity of the copolyesters were
found to be affected by the kind of organic phase, contribution of
benzyltriethylammonium chloride as a catalyst, the quantitative ratio of organic to
aqueous phase, concentration of hydrogen chloride acceptor and time of addition of
the acid chloride. The resulting copolyesters were characterized by elemental and
spectral analyses. Moreover, the various characteristics of the various types of
prepared copolymers including: solubility, viscosity, X-ray diffraction analysis, DSC
and TGA were determined and discussed. The electrical properties of the copolyesters
were tested and the morphology of selected examples of the copolyesters was
examined by scanning electron microscopy.

Research Authors
Kamal I. Aly, Ahmed S. Hammam, Shaban M. Radwan, and Mona A. Abdel-Rahman
Research Department
Research Journal
International Journal of Basic & Applied Sciences IJBAS-IJENS
Research Pages
PP.15-35
Research Rank
1
Research Vol
Vol: 11 No: 04
Research Year
2011

New Unsaturated Copolyesters based on
Diarylidenecyclopentanone. Optimum conditions of
Synthesis, Characterization and Morphology.

Research Abstract

A new interesting series of linear, unsaturated copolyesters containing
cyclopentanone moiety in the main chain were synthesized by interfacial
polycondensation of a mixture containing one mole of both monomeric units 2,5-bis
(4-hydroxybenzylidene) cyclopentanone (Ia) and 2,5-bis (4-hydroxy-3-
methoxybenzylidene) cyclopentanone (Ib) together with two moles of different acid
chlorides. The yield and the values of reduced viscosity of the copolyesters were
found to be affected by the kind of organic phase, contribution of
benzyltriethylammonium chloride as a catalyst, the quantitative ratio of organic to
aqueous phase, concentration of hydrogen chloride acceptor and time of addition of
the acid chloride. The resulting copolyesters were characterized by elemental and
spectral analyses. Moreover, the various characteristics of the various types of
prepared copolymers including: solubility, viscosity, X-ray diffraction analysis, DSC
and TGA were determined and discussed. The electrical properties of the copolyesters
were tested and the morphology of selected examples of the copolyesters was
examined by scanning electron microscopy.

Research Authors
Kamal I. Aly, Ahmed S. Hammam, Shaban M. Radwan, and Mona A. Abdel-Rahman
Research Department
Research Journal
International Journal of Basic & Applied Sciences IJBAS-IJENS
Research Pages
PP.15-35
Research Rank
1
Research Vol
Vol: 11 No: 04
Research Year
2011

Liquid crystalline polymers VIII: thermotropic liquid
crystalline poly(hydrazone–ether)s containing bis-thiophene
linked to the main chain through spacers of various lengths

Research Abstract

Anewseries of poly(hydrazone–ether)swas synthesized from 3,4-dimethylthieno [2,3-b] thiophene-2,
5-dicarbohydrazide, II and 4,4-diformyl-α, ω-diphenoxyalkanes or 4,4-diformyl -2,2-dimethoxy -α,
ω-diphenoxyalkanes. The inherent viscosities of the polymers were in the range 0.22 – 0.56 dIg−1.
Majority of the polymers were soluble in concentrated H2SO4. Their thermotropic liquid crystalline
properties were examined by DSC, an optical polarizing microscopy using a hot stage and thermogravimetric
analyses. The polymers exhibited almost thermotropic liquid crystalline properties. In
most cases, the mesophases extended up to 430◦C, where thermal decomposition prevented further
observation.

Research Authors
A. S. HAMMAM, K. I. ALY, Sh. M. RADWAN and M. A. ABDEL-RAHMAN
Research Department
Research Journal
Journal of Sulfur Chemistry
Research Member
Research Pages
PP.547–561
Research Rank
1
Research Vol
Vol. 28, No. 6
Research Year
2007

Liquid crystalline polymers VIII: thermotropic liquid
crystalline poly(hydrazone–ether)s containing bis-thiophene
linked to the main chain through spacers of various lengths

Research Abstract

Anewseries of poly(hydrazone–ether)swas synthesized from 3,4-dimethylthieno [2,3-b] thiophene-2,
5-dicarbohydrazide, II and 4,4-diformyl-α, ω-diphenoxyalkanes or 4,4-diformyl -2,2-dimethoxy -α,
ω-diphenoxyalkanes. The inherent viscosities of the polymers were in the range 0.22 – 0.56 dIg−1.
Majority of the polymers were soluble in concentrated H2SO4. Their thermotropic liquid crystalline
properties were examined by DSC, an optical polarizing microscopy using a hot stage and thermogravimetric
analyses. The polymers exhibited almost thermotropic liquid crystalline properties. In
most cases, the mesophases extended up to 430◦C, where thermal decomposition prevented further
observation.

Research Authors
A. S. HAMMAM, K. I. ALY, Sh. M. RADWAN and M. A. ABDEL-RAHMAN
Research Department
Research Journal
Journal of Sulfur Chemistry
Research Member
Research Pages
PP.547–561
Research Rank
1
Research Vol
Vol. 28, No. 6
Research Year
2007

Liquid crystalline polymers VIII: thermotropic liquid
crystalline poly(hydrazone–ether)s containing bis-thiophene
linked to the main chain through spacers of various lengths

Research Abstract

Anewseries of poly(hydrazone–ether)swas synthesized from 3,4-dimethylthieno [2,3-b] thiophene-2,
5-dicarbohydrazide, II and 4,4-diformyl-α, ω-diphenoxyalkanes or 4,4-diformyl -2,2-dimethoxy -α,
ω-diphenoxyalkanes. The inherent viscosities of the polymers were in the range 0.22 – 0.56 dIg−1.
Majority of the polymers were soluble in concentrated H2SO4. Their thermotropic liquid crystalline
properties were examined by DSC, an optical polarizing microscopy using a hot stage and thermogravimetric
analyses. The polymers exhibited almost thermotropic liquid crystalline properties. In
most cases, the mesophases extended up to 430◦C, where thermal decomposition prevented further
observation.

Research Authors
A. S. HAMMAM, K. I. ALY, Sh. M. RADWAN and M. A. ABDEL-RAHMAN
Research Department
Research Journal
Journal of Sulfur Chemistry
Research Pages
PP.547–561
Research Rank
1
Research Vol
Vol. 28, No. 6
Research Year
2007

Liquid crystalline polymers VIII: thermotropic liquid
crystalline poly(hydrazone–ether)s containing bis-thiophene
linked to the main chain through spacers of various lengths

Research Abstract

Anewseries of poly(hydrazone–ether)swas synthesized from 3,4-dimethylthieno [2,3-b] thiophene-2,
5-dicarbohydrazide, II and 4,4-diformyl-α, ω-diphenoxyalkanes or 4,4-diformyl -2,2-dimethoxy -α,
ω-diphenoxyalkanes. The inherent viscosities of the polymers were in the range 0.22 – 0.56 dIg−1.
Majority of the polymers were soluble in concentrated H2SO4. Their thermotropic liquid crystalline
properties were examined by DSC, an optical polarizing microscopy using a hot stage and thermogravimetric
analyses. The polymers exhibited almost thermotropic liquid crystalline properties. In
most cases, the mesophases extended up to 430◦C, where thermal decomposition prevented further
observation.

Research Authors
A. S. HAMMAM, K. I. ALY, Sh. M. RADWAN and M. A. ABDEL-RAHMAN
Research Department
Research Journal
Journal of Sulfur Chemistry
Research Pages
PP.547–561
Research Rank
1
Research Vol
Vol. 28, No. 6
Research Year
2007

Control of sesame wilt and charcoal rot diseases by intact or sonicated
cells of Nostoc sp SAG2306

Research Abstract

Biological control of Fusarium salani (Mart) Sacc. and Macrophomina phaseolina (Tassi) Goid
causing wilt and charcoal rot diseases of Sesame (Sesamum indicum Linn) was studied in vitro as
well as under pot conditions. Culture technique showed that the addition of intact Nostoc sp
SAG2306 or its sonicate inhibited the radial mycelial growth of the test pathogens. Application of
Nostoc sonicates resulted in the lowest infection percentage (11.11 % and 17.78 % of Fusarium and
Macrophomina respectively) whereas in the control it was 95.55%. Under pot conditions, plant
height, fresh and dry weight of plants was found to increase significantly as a result of the inhibition
of fungal by Nostoc. Similar results were observed in chlorophyll (ch.la&ch.lb) content of the treated
plants. Infection enhanced proline accumulation that was lowered upon Nostoc addition; indicating
alleviation of infection ascribed stress.

Research Authors
Hoda A.H. Ahmed, Fatma A. Farghaly, Awatief F. Hifney and R. Abdel-Basset
Research Journal
Jokull Journal
Research Rank
1
Research Vol
Vol 63, No. 9
Research Year
2013

Control of sesame wilt and charcoal rot diseases by intact or sonicated
cells of Nostoc sp SAG2306

Research Abstract

Biological control of Fusarium salani (Mart) Sacc. and Macrophomina phaseolina (Tassi) Goid
causing wilt and charcoal rot diseases of Sesame (Sesamum indicum Linn) was studied in vitro as
well as under pot conditions. Culture technique showed that the addition of intact Nostoc sp
SAG2306 or its sonicate inhibited the radial mycelial growth of the test pathogens. Application of
Nostoc sonicates resulted in the lowest infection percentage (11.11 % and 17.78 % of Fusarium and
Macrophomina respectively) whereas in the control it was 95.55%. Under pot conditions, plant
height, fresh and dry weight of plants was found to increase significantly as a result of the inhibition
of fungal by Nostoc. Similar results were observed in chlorophyll (ch.la&ch.lb) content of the treated
plants. Infection enhanced proline accumulation that was lowered upon Nostoc addition; indicating
alleviation of infection ascribed stress.

Research Authors
Hoda A.H. Ahmed, Fatma A. Farghaly, Awatief F. Hifney and R. Abdel-Basset
Research Journal
Jokull Journal
Research Member
Research Rank
1
Research Vol
Vol 63, No. 9
Research Year
2013

Control of sesame wilt and charcoal rot diseases by intact or sonicated
cells of Nostoc sp SAG2306

Research Abstract

Biological control of Fusarium salani (Mart) Sacc. and Macrophomina phaseolina (Tassi) Goid
causing wilt and charcoal rot diseases of Sesame (Sesamum indicum Linn) was studied in vitro as
well as under pot conditions. Culture technique showed that the addition of intact Nostoc sp
SAG2306 or its sonicate inhibited the radial mycelial growth of the test pathogens. Application of
Nostoc sonicates resulted in the lowest infection percentage (11.11 % and 17.78 % of Fusarium and
Macrophomina respectively) whereas in the control it was 95.55%. Under pot conditions, plant
height, fresh and dry weight of plants was found to increase significantly as a result of the inhibition
of fungal by Nostoc. Similar results were observed in chlorophyll (ch.la&ch.lb) content of the treated
plants. Infection enhanced proline accumulation that was lowered upon Nostoc addition; indicating
alleviation of infection ascribed stress.

Research Authors
Hoda A.H. Ahmed, Fatma A. Farghaly, Awatief F. Hifney and R. Abdel-Basset
Research Journal
Jokull Journal
Research Rank
1
Research Vol
Vol 63, No. 9
Research Year
2013
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