We report an economical approach for the fabrication of laser-produced graphene (LPG) electrodes, which results in an improved electrochemical performance. Polyimide polymer was used as the starting material for LPG synthesis and was irradiated under ambient conditions with a CO2 laser. The prepared LPG samples were characterized by Raman spectroscopy and FTIR, which validated the formation of multilayer graphene containing sp2 hybridized C＝C bonds. FE-SEM revealed three-dimensional (3D) sheet-like structures, while HR-TEM images showed lattice planes with an interplanar spacing of approximately 0.33 nm, corresponding to the (002) plane of graphene. Their electrochemical performance showed a remarkable areal specific capacitance (CA) of 51 mF cm−2 (170 F g−1) at 1 mA cm−2 (3.3 A g−1) in a three-electrode configuration with 1 mol L−1 KOH as the aqueous electrolyte. The LPG electrodes produced an energy density of ~3.5 µWh cm−2 and a power density of ~350 µW cm−2, demonstrating significant energy storage ability. They also had an excellent cycling stability, retaining 87% of their specific capacitance after 3 000 cycles at 1 mA/cm2. A symmetric supercapacitor fabricated with LPG electrodes and the 1 mol L−1 KOH electrolyte had a specific capacitance of 23 mF cm−2 and showed excellent retention after 10 000 cycles, showing LPG’s potential for use in supercapacitors. Key words: Supercapacitors; Graphene; LPG; Electrochemical studies; Charge storage mechanism