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F!CN Bond Cleavage by Iron Silyl
Complex and Electronic Effect of the
Group or Atom Attached to Cyano
Group: A Theoretical DFT Study

Research Abstract
The cleavage of F!CN bond in the presence of Fe(II) silyl complex, [Cp(CO)FeSiMe3], was studied using density functional theory calculations and compared with the mechanisms for E!CN (E = C, N, and O) bond cleavages, which have previously been clarified to be a silyl-migration-induced reaction.
Research Authors
AbdelRahman A. Dahy and Nobuaki Koga
Research Department
Research Journal
Bull of the Chemical Society of Japan
Research Pages
PP.273-275
Research Rank
1
Research Vol
Vol. 86, No. 2
Research Year
2013